The invention discloses an alkali-added wet type oxidation catalytic desulfurization waste solution recycling method. The method comprises the following steps of: pressurizing a desulfurization solution into a filter via a pump, then entering a decoloring kettle, adding activated carbon to decolor the desulfurization solution, pressurizing into a sulfo-evaporation kettle through the pump via a decoloring storage tank, evaporating the solution to a certain concentration in the evaporation kettle, placing into the filter for filtering, then crystallizing filtrate, and finally separating in a centrifuge to obtain a Na2S2O3 product; and pressing the filtrate after centrifugation into a SCN-evaporation kettle through the pump via a storage kettle, evaporating the solution to a certain concentration in the evaporation kettle, placing into the filter for filtering, enabling the filtrate to enter the SCN-evaporation kettle for crystallization, then separating in the centrifuge to obtain a rough NaCNS product, performing two times of solution, decoloring, evaporation and crystallization on the rough product, and then separating in the centrifuge to obtain a final fine NaCNS product. According to the method disclosed by the invention, the mature and advanced filtration, concentration, crystallization and separation process flows are selected, and all process sections are mutually linked and supplement each other, so that the optimization of the whole process is achieved.