The invention discloses a thermal stable diaphragm material for a
lithium ion battery and a preparation method of the thermal stable diaphragm material, and the material solves the key problems of easy
thermal runaway, deformation shrinkage, channel blockage and the like of the existing diaphragm under extreme working conditions by synergistically constructing a three-dimensional
composite structure with high
thermal stability, mechanical flexibility and
ion permeability. The flexible
lithium battery diaphragm has good large-scale preparation capability and
engineering application prospect,
cement which is a traditional
building material is introduced into a flexible
lithium battery diaphragm
system for the first time, and a multi-scale synergistic
ion guide channel
system is constructed by utilizing the high
thermal stability and natural
porosity of the
cement and combining a
polymer flexible phase and an in-situ foaming process. The strategy not only realizes the morphological stability and
thermal protection capability of the material under a high-temperature condition, but also significantly improves the
ion permeability and interface electrochemical suitability, and breaks through the problem of performance balance between thermal stress and flexibility of the existing
polyolefin and inorganic
coating diaphragm. Besides, the whole
system adopts low-cost raw materials, the preparation process can be completed under normal-temperature and normal-pressure conditions, high-temperature
sintering,
electrospinning or vacuum treatment is not needed, and the industrial popularization potential is extremely high.