The invention provides an ultra-low-expansion glass ceramic for a laser gyro and a preparation method thereof, wherein, the ultra-low-expansion glass ceramic includes the following ingredients according to mass percentages: 56-68% of SiO2, 21-27% of Al2O3, 2-4% of Li2, 0-1% of Na2, 0-1% of K2, 0-3% of MgO, 0-1.5% of ZnO, 4.5-6.8% of P2O5, 1-2.5% of TiO2, 1-2.5% of ZrO2 and 0.5-1.5% of Sb2O3/As2O3; the principal crystalline phase is beta quartz solid solution; the crystalline phase content is 70-85%; the grain size is lower than 50nm; and the magnitude order of coefficient of heat expansion is 10<-8>. The preparation method comprises the steps of dosing, mixing, melting, evening, clarifying, glass moulding, annealing and sitallization heat treatment, wherein, the steps of melting, evening and clarifying are carried out at 1570-1590 DEG C; the sitallization heat treatment comprises the steps as follows: the materials are crystallized after 6-10 hours of warm keeping at nucleating temperature of 650-750 DEG C with crystallizing rate of 1 DEG C/min; the crystallizing temperature is 750-850 DEG C; and the warm-keeping time is 6-10 hours. The buckling strength of the ultra-low expansion glass ceramic is higher than 170MPa; the process roughness is higher than 2-star; and the spectrum transmittance is more than 90% within the waveband of 0.6-2mum. In addition, the ultra-low-expansion glass ceramic has excellent hardness and abrasion resistance.