5 results about "Fluoride crystals" patented technology

This invention provides a thorium-doped fluoride crystal, its preparation method, and a solid-state nuclear optical clock using the thorium-doped fluoride. The thorium-doped fluoride crystal uses SrF2, LiF, BaF2, and LiF+BaF2 as matrix materials, respectively, and ThF4 as a dopant material. Single crystals of Th:SrF2, Th:LiF, Th:BaF2, and Th:BaLiF3 are obtained through a melt growth process according to a pre-set molar percentage of the raw materials. The thorium-doped fluoride crystal of this invention has a low melting point and simple composition, which is beneficial for achieving high-quality crystal growth. It has an extremely wide band gap, high transmittance in the vacuum ultraviolet band, and a high Th doping concentration, which helps reduce absorption loss and background luminescence in the nuclear transition emission band, and is beneficial for the excitation and detection of nuclear transition signals. It can be used as a preferred material for applications based on… 229 A solid-state nuclear optical clock based on the transition of the Th atom nucleus.

This invention belongs to the field of rare-earth luminescent materials and optical sensing technology, specifically disclosing an upconversion temperature probe excited by NIR-I, its preparation method, and its application. The probe includes a matrix core material, which is a fluoride crystal; and dopant ions, specifically holmium ions (Ho) doped into the matrix core material. 3+ Ho 3+ As the sole luminescent center, it is excited by a near-infrared I light source with a wavelength of 880-920 nm to generate Ho. 3+ Characteristic green upconversion luminescence and red upconversion luminescence. This invention employs the aforementioned NIR-I excited upconversion temperature probe, its preparation method, and its application, utilizing Ho... 3+ The unique energy level competition mechanism of ions enables high-sensitivity temperature measurement over a wide temperature range, and the temperature measurement signal is unaffected by fluctuations in excitation power.

This application relates to the field of fluoride-containing wastewater treatment technology, and particularly to a system and method for recovering fluorides from fluoride-containing wastewater. The system includes a raw material zone, a sedimentation zone, and a detection zone. The raw material zone includes a first feeding unit for storing the fluoride-containing wastewater and a second feeding unit for storing a precipitant solution. The sedimentation zone includes a sedimentation chamber, and the detection zone includes a detection chamber, the bottom of which is connected to the top of the sedimentation chamber. Fluoride seed crystals are present in the sedimentation chamber. The first feeding unit delivers the fluoride-containing wastewater to the bottom of the sedimentation chamber, and the second feeding unit delivers the precipitant solution to the bottom of the sedimentation chamber. The fluoride-containing wastewater and the precipitant solution mix to form a mixed solution, which then reacts on the surface of the fluoride seed crystals to form fluoride crystals. The detection chamber is used by an operator to detect the fluoride content and turbidity in the mixed solution and to discharge the supernatant. When the reaction is complete, the fluoride crystals in the sedimentation chamber are removed. This system for recovering fluorides from fluoride-containing wastewater exhibits high fluoride recovery efficiency and quality.