19 results about "Fluoride crystals" patented technology

The present invention provides defect-controlled fluoride crystals, a method for producing the same, and the use thereof. These fluoride crystals contain at least a rare earth element RE (RE is at least one element selected from the group consisting of cerium (Ce), praseodymium (Pr), lanthanum (La), and neodymium (Nd)), fluorine (F), and hydrogen (H), and have the same crystal structure as crystals represented by CeF3. A method for producing fluoride crystals according to the present invention comprises growing crystals from a raw material containing a rare earth element RE and a raw material containing fluorine (F) by a solvothermal method in the presence of at least one mineralizer selected from the group consisting of mineralizers containing an alkali metal element and / or an alkaline earth metal element, acid mineralizers, and mineralizers containing a normal salt.

The invention discloses a closed growth method of a high-purity laser-damage-resistant fluoride crystal, and relates to the technical field of crystal growth. The preparation method comprises the following steps: treating fluoride powder with an HF solution, and performing F2 high-temperature roasting purification; growing crystals in a Bridgman furnace under the assistance of a uniform magnetic field with proper intensity; and finally, processing the crystal by using CF4 and O2 mixed gas plasma to eliminate crystal surface damage and form a fluorine-rich passivation layer. Heat convection in the melt can be inhibited through assistance of the magnetic field, the crystallization process is kept stable, the impurity content and dislocation density of the crystal can be effectively reduced, the laser damage resistance of the crystal is improved, and the method is suitable for the high-end optical field.

The invention relates to a method for realizing bonding growth of rare earth doped fluoride and pure fluoride crystals, and belongs to the technical field of crystal growth. Aiming at the technical problems of high requirement on polishing quality of a pre-bonding surface, sudden change of refractive index of a bonding interface, limited bonding area and the like in the existing crystal bonding method, one of a pure fluoride host crystal or a rare earth doped fluoride crystal is selected as a seed crystal; then weighing and mixing the raw materials according to the stoichiometric ratio of another bonded crystal component, pressing the raw materials into a raw material block, finally putting the seed crystal and the raw material block into a crucible in sequence, and realizing the bonding growth of the rare earth doped fluoride and pure fluoride crystal by adopting a temperature gradient method or a Bridgman-Stockbarger method. And finally obtaining the composite crystal formed by bonding the pure fluoride crystal and the rare earth ion doped fluoride crystal. According to the composite crystal grown by the method, sudden change of the refractive index at the bonding interface is avoided, the preparation cost of the composite crystal element is reduced, and the laser performance of the bonding gain element is improved.

An adaptive annealing crucible for large-size fluoride crystals includes: a crucible base having an inner ring located radially inward, an outer ring located radially outward, and a lower adaptive layer connecting the inner and outer rings; a crucible lid having an inner ring located radially inward, an outer ring located radially outward, and an upper adaptive layer connecting the inner and outer rings; an inner crucible cylinder composed of multiple segmented structures, movably and vertically disposed between the inner ring of the base and the inner ring of the lid; and the inner cylinder being capable of radial expansion and contraction; and a guiding structure for defining the direction of expansion and contraction of the inner cylinder. This invention solves the problem that crystals cannot freely expand and contract during annealing, resulting in the inability to release stress within the crystal.

This invention provides a thorium-doped fluoride crystal, its preparation method, and a solid-state nuclear optical clock using the thorium-doped fluoride. The thorium-doped fluoride crystal uses SrF2, LiF, BaF2, and LiF+BaF2 as matrix materials, respectively, and ThF4 as a dopant material. Single crystals of Th:SrF2, Th:LiF, Th:BaF2, and Th:BaLiF3 are obtained through a melt growth process according to a pre-set molar percentage of the raw materials. The thorium-doped fluoride crystal of this invention has a low melting point and simple composition, which is beneficial for achieving high-quality crystal growth. It has an extremely wide band gap, high transmittance in the vacuum ultraviolet band, and a high Th doping concentration, which helps reduce absorption loss and background luminescence in the nuclear transition emission band, and is beneficial for the excitation and detection of nuclear transition signals. It can be used as a preferred material for applications based on… 229 A solid-state nuclear optical clock based on the transition of the Th atom nucleus.

This invention belongs to the field of rare-earth luminescent materials and optical sensing technology, specifically disclosing an upconversion temperature probe excited by NIR-I, its preparation method, and its application. The probe includes a matrix core material, which is a fluoride crystal; and dopant ions, specifically holmium ions (Ho) doped into the matrix core material. 3+ Ho 3+ As the sole luminescent center, it is excited by a near-infrared I light source with a wavelength of 880-920 nm to generate Ho. 3+ Characteristic green upconversion luminescence and red upconversion luminescence. This invention employs the aforementioned NIR-I excited upconversion temperature probe, its preparation method, and its application, utilizing Ho... 3+ The unique energy level competition mechanism of ions enables high-sensitivity temperature measurement over a wide temperature range, and the temperature measurement signal is unaffected by fluctuations in excitation power.

The application discloses an explosion-proof window structure and a preparation method and application thereof, relates to the technical field of explosion-proof window structures, and comprises the following steps: mixing inorganic nano-particles modified with perfluoropolyether to prepare a composite functional coating; spraying the composite functional coating onto the surface of a fluoride crystal to prepare a light-transmitting element; and assembling the light-transmitting element with a sealing assembly, a mounting and fixing assembly, a flange frame and a protective cover to obtain an explosion-proof window structure. The window structure improves the explosion-proof performance of the light-transmitting element through the physical structure and the performance enhancement of the light-transmitting element, maintains the excellent light-transmitting property of the light-transmitting element, and has wide application value.

The invention discloses a fluoride crystal bar processing machine tool, and relates to the technical field of semiconductor material processing, a cutting assembly in the machine tool comprises a base, a carborundum line arranged on the base, and a fixing frame arranged on the base; the adjusting assembly comprises a motor, a screw rod connected with the motor, a sliding block connected with the screw rod, a connecting rod connected with the sliding block, an adjusting frame arranged on the fixing frame, an adjusting rod arranged on the adjusting frame and a rotating block arranged on the adjusting rod. The feeding assembly comprises a mounting frame, a moving seat arranged on the mounting frame, a clamp arranged on the moving seat and an inclined frame arranged on the mounting frame. The cutting path of the crystal bar can be changed from a straight line to a controllable curved surface through the adjusting assembly, which is crucial to machining of optical crystal elements needing specific curved surface shapes, and the machining capacity of a machine tool is greatly expanded.

The invention discloses a novel fluoride crystal pulling thermal field. A novel fluoride crystal pulling thermal field comprises a thermal field body, bottom heating supporting legs are fixed to a bottom heat preservation structure of the thermal field body, and the bottom heating supporting legs are detachably connected with a bottom heater; the bottom heating supporting legs are positioned on the periphery of the graphite shaft; the bottom heat preservation structure is sleeved with a lower soaking cylinder, the lower soaking cylinder is located on the periphery of the bottom heater, and the side heater is located on the periphery of the lower soaking cylinder. The interior of the heat preservation cavity is divided up and down through a filter graphite supporting ring, a filtering assembly and an upper soaking cylinder which are arranged inside and outside are installed above the filter graphite supporting ring, the top of the filtering assembly is sleeved with a flow guide cylinder, the top of the flow guide cylinder is higher than the top of the filtering assembly, and air holes are formed in the upper soaking cylinder; and the filter graphite supporting ring is erected above the lower soaking cylinder and is provided with an air guide pipe which is butted and communicated with the upper cavity. According to the invention, the stability and quality of fluoride crystal pulling are realized.

This invention relates to the field of crystal detection technology, specifically to a method for detecting the dislocation density of fluoride crystals, particularly suitable for the dislocation density analysis of calcium fluoride crystals. The method comprises: (1) pre-treating the surface of the fluoride crystal to be tested; (2) corroding the surface of the fluoride crystal to be tested using a corrosion mixture solution, followed by termination of corrosion, wherein the corrosion mixture solution is used to form corrosion pits on the surface of the fluoride crystal to be tested; (3) observing the surface of the fluoride crystal to be tested, counting the number of corrosion pits in the fluoride crystal to be tested, and calculating the dislocation density of the fluoride crystal to be tested based on the number of corrosion pits, wherein the corrosion pits are corrosion pits with dislocation characteristics among the corrosion pits.

The invention belongs to the technical field of single crystal optical fiber growth, and relates to a method for growing a rare earth ion doping concentration gradient distribution composite single crystal optical fiber by using a laser heating base (LHPG) method by taking a thermal bonding crystal as a source rod. The preparation method comprises the following steps: adopting a thermal bonding crystal with a sandwich structure as a source rod, and growing a composite single crystal optical fiber with rare earth ion doping concentration in gradient distribution by using a laser heating base method; wherein the thermal bonding crystal takes a pure fluoride crystal as two end parts and a rare earth ion doped fluoride crystal as the middle part, or takes a pure garnet type oxide crystal as two end parts and a rare earth ion doped garnet type oxide crystal as the middle part. The diameter phi of the grown composite single crystal optical fiber can reach 0.2-2.0 mm, the growth speed can reach 10-150 mm / h, and the grown single crystal optical fiber can be used in the fields of solid laser, radiation detection and the like.

This application relates to the field of fluoride-containing wastewater treatment technology, and particularly to a system and method for recovering fluorides from fluoride-containing wastewater. The system includes a raw material zone, a sedimentation zone, and a detection zone. The raw material zone includes a first feeding unit for storing the fluoride-containing wastewater and a second feeding unit for storing a precipitant solution. The sedimentation zone includes a sedimentation chamber, and the detection zone includes a detection chamber, the bottom of which is connected to the top of the sedimentation chamber. Fluoride seed crystals are present in the sedimentation chamber. The first feeding unit delivers the fluoride-containing wastewater to the bottom of the sedimentation chamber, and the second feeding unit delivers the precipitant solution to the bottom of the sedimentation chamber. The fluoride-containing wastewater and the precipitant solution mix to form a mixed solution, which then reacts on the surface of the fluoride seed crystals to form fluoride crystals. The detection chamber is used by an operator to detect the fluoride content and turbidity in the mixed solution and to discharge the supernatant. When the reaction is complete, the fluoride crystals in the sedimentation chamber are removed. This system for recovering fluorides from fluoride-containing wastewater exhibits high fluoride recovery efficiency and quality.

The utility model discloses a fixing device for polishing fluoride crystal bars, which comprises a crystal bar disc and cover plates, the crystal bar disc comprises a disc, the outer edge of the disc is provided with a plurality of grooves, the grooves are used for placing crystal bars, and one groove at least corresponds to one cover plate; the cover plate is arranged corresponding to the grooves, the cover plate comprises a main body and second bulges arranged corresponding to the grooves, the end parts of the two sides of the main body are connected with the disc, and the crystal bars in the corresponding grooves are locked through the cover plate. During use, a crystal bar is placed in the groove, the bottom face of the crystal bar slightly exceeds the crystal bar disc, after positioning is completed, the crystal bar is fixed through glue injection, the opening of the groove is covered with the cover plate to be locked, and then the crystal bar and the crystal bar disc can form a whole to be fixed to a polishing machine to polish the end of the crystal bar. The fixing device for polishing the fluoride crystal bar further has the advantages that the polishing process is stable, the stress point height in the crystal bar machining process is reduced, materials are saved, and machining is flexible.

This invention belongs to the field of fluoride crystal annealing technology, specifically relating to an annealing crucible and annealing method for fluoride crystals. The annealing crucible includes: an outer crucible; and an inner crucible disposed inside the outer crucible. The inner crucible has multiple through holes and is used to place the fluoride crystal and a protective material. The protective material covers the fluoride crystal to prevent direct contact between the fluoride crystal and the inner crucible and air. A gap layer is provided between the inner and outer crucibles to fill with fragmented crystal material. The annealing crucible can selectively allow at least a portion of the protective material to overflow into the gap layer along the through holes. The "double-layer crucible" structure of this invention, combining the outer crucible and the through-hole inner crucible, provides a buffer space for the expansion of the fluoride crystal during annealing, effectively reducing the axial and radial temperature gradients of the crystal, generating a more uniform annealing environment, and allowing the internal stress of the crystal to be released slowly.

To provide defect-controlled fluoride crystals, methods for producing the same, and their applications. [Solution] The fluoride crystal of the present invention contains cesium (Cs), rare earth element RE, and fluorine (F), and has the general formula CsRE2F 7-x The inorganic crystal represented by (where x satisfies 0 ≤ x ≤ 0.5) contains at least hydrogen (H). The present invention relates to a method for producing fluoride crystals, which involves growing crystals by solvothermal method from a raw material containing a rare earth element RE and a raw material containing a fluorine element (F) in the presence of a mineralizing agent containing at least cesium element (Cs).

The invention discloses an optical property prediction method of a fluoride laser crystal based on deep learning, which belongs to the technical field of deep learning and material science and comprises the following steps: constructing a source domain data set of the fluoride crystal with a crystal stability label, and training a source domain model by taking structural parameters and a chemical formula of the fluoride crystal as input to obtain a source domain model; obtaining a crystal stability prediction model; the constructed optical property prediction model comprises a feature extractor and a detection head which are connected in sequence, and the feature extractor is a structure branch GNN and a component branch CoTAN in the crystal stability prediction model; the detection head is used for mapping the features extracted by the feature extractor into a prediction result of the optical properties of the crystal; and inputting the obtained structure parameters and the chemical formula of the fluoride laser crystal to be predicted into the optical property prediction model to obtain an optical property prediction result. According to the method, the crystal stability prediction model is introduced into the optical property prediction process through transfer learning, the problem of scarcity of crystal optical data is solved, and the model prediction precision is improved.

The present application relates to a kind of rare earth doped alkaline earth fluoride / alkaline earth fluoride bonded crystal and its preparation method.The preparation method of the rare earth doped alkaline earth fluoride / alkaline earth fluoride bonded crystal includes the following steps:(1) polishing, cleaning preparation rare earth doped alkaline earth fluoride RE:MF2 Crystal and alkaline earth fluoride MF2 Crystal pre-bonding piece of bonding surface;(2) RE:MF2 Crystal and MF2 Crystal pre-bonding piece is placed on the optical cement body with the direction of bonding surface opposite to each other with heat, pressure is applied to make the bonding surface of two crystals closely abut, obtain crystal optical cement pre-bonding piece;(3) crystal optical cement pre-bonding piece is fixed and by stainless steel spring perpendicular to bonding surface again 0.2-5MPa is applied pressure, MF2 Crystal powder is used to embed the crystal optical cement pre-bonding piece, heat treatment is carried out in muffle furnace at 400-650 ℃ temperature, obtain the rare earth doped alkaline earth fluoride / alkaline earth fluoride bonded crystal.

The invention relates to a method for growing rare earth gradient doped fluoride laser crystals, and belongs to the technical field of crystal growth. Aiming at the technical problem that the rare earth ion concentration distribution in the rare earth doped fluoride crystal is difficult to realize manual design or regulation, the invention adopts a microporous crucible comprising an upper loading bin, a lower loading bin and a single crystal growth through hole which is communicated with the upper loading bin and extends in the vertical direction. The preparation method comprises the following steps: firstly, placing a rare earth doped fluoride laser crystal raw material block with relatively high doping content in a lower loading bin, placing rare earth doped fluoride laser crystal raw material powder with relatively low doping content in an upper loading bin, and filling a single crystal growth through hole with the rare earth doped fluoride laser crystal raw material powder; the rare earth gradient doped fluoride laser crystal can be grown by utilizing the inhibition effect of the small-caliber through hole in the crucible on melt convection, and the concentration gradient of the grown rare earth doped crystal can be manually regulated and controlled by adjusting parameters such as heat preservation time and the like.