The invention relates to the technical field of seawater desalination, and provides a falling film condenser of a low-temperature multi-effect distillation seawater desalination system, a heat exchange tube support frame is arranged in a condenser shell, five groups of water chambers are arranged on the heat exchange tube support frame, and the water chambers are divided into two layers, two groups of upper layers and three groups of lower layers; the water chamber comprises a first channel heat exchange tube bundle set, a second channel heat exchange tube bundle set and a spraying tube bundle, the first channel heat exchange tube bundle set and the second channel heat exchange tube bundle set comprise a plurality of heat exchange tube bundles, the first channel heat exchange tube bundle set is arranged on the lower side of the second channel heat exchange tube bundle set, and the spraying tube bundle is arranged on the upper side of the second channel heat exchange tube bundle set. According to the heat exchange tube bundle assembly, the problems that in a conventional design, a heat exchange tube bundle is small in heat exchange area, low in waste heat recovery rate, tedious in leakage inspection and replacement, extremely prone to scouring and electrochemical corrosion and the like are solved.