The invention discloses solvent-free graphene oxide-glass flake anticorrosive coating. The solvent-free graphene oxide-glass flake anticorrosive coating is prepared from an A component and a B component, wherein the A component is prepared from glass flakes modified by graphene oxide, an epoxy resin, an aqueous polyurethane resin, castor oil, reactive diluent, aluminum tripolyphosphate, talc, antifoaming agent and titanium dioxide; the B component is prepared from an epoxy curing agent H633, when used, the A component and the B component are uniformly mixed with the mass ratio of 1 to (0.2 to0.25). According to the solvent-free graphene oxide-glass flake anticorrosive coating provided by the invention, through the glass flakes modified by graphene oxide, on the one hand, the conditions that a graphene oxide sheet layer is evenly spread on the surface of the glass flakes and fills pores at joints between the glass flakes and flakes in a spreading state are realized, thereby improving ashielding ability of the glass flakes, and on the other hand, low temperature curing, and enhancement of the adhesion of the glass flakes in the coating are realized. The solvent-free graphene oxide-glass flake anticorrosive coating has strong adhesion, impact resistance and better salt tolerance.