The invention relates to a wearable high-precision data acquisition upper limb exoskeleton, comprising an adjustable base, a shoulder rotation pair mechanism, a shoulder slide ring mechanism, an upper arm connecting rod length sliding adjusting mechanism, an elbow parallel rotation pair mechanism, an elbow slide ring mechanism, a lower arm connecting rod length sliding adjusting mechanism, a wrist rotation pair mechanism, a tail end operation handle and a tool clamping device. A high-precision photoelectric encoder is mounted on each joint, the position and the posture of a tail end can be accurately acquired via forward kinematics, and a manipulator can be accurately controlled. The wearable high-precision data acquisition upper limb exoskeleton is compact in structure, light in weight and high in rigidity, is applicable to different operation heights and arm lengths, two control buttons are arranged on the handle to control procedures of an upper computer, and the exoskeleton further can be used as a guiding hand to be used for realizing upper limb exercise rehabilitation training of hemiplegia patients.