The invention discloses a process method of a non-self-aligned high-
voltage CMOS (complementary
metal oxide semiconductor) device. The method comprises the following steps: providing a
semiconductor substrate and forming a
shallow trench isolation structure comprising a chemical mechanical
polishing stop layer; patterning the stop layer in a preset high-
voltage device area to form a
hard mask with a trapezoidal cross section (a preset angle theta formed by a bevel edge and the substrate is smaller than 90 degrees); before a well region is formed, carrying out inclined lightly doped drain
electrode ion implantation by using the trapezoidal
hard mask; and then the
hard mask is removed, and a well region, a gate structure covering a channel region, a source
electrode heavily doped region and a drain
electrode heavily doped region are sequentially formed. The hard
mask with the inclined side wall is combined with inclined injection,
doping distribution of the lightly-doped drain electrode can be effectively optimized, the overlapping area of the grid electrode and the drain electrode is enlarged, and meanwhile injection of the lightly-doped drain electrode can increase the follow-up thermal process and improve the
hot carrier injection performance in advance. The method improves the
voltage resistance and reliability of the device, reduces the electric leakage, is good in process compatibility, and does not affect the shape of the grid electrode.