The invention discloses a preparation method of wear-resistant decorative paper, comprising the following steps, S1: heating, stirring and fully mixing 50-100 parts of alumina powder, 500-1500 parts of deionized water, 1-3 parts of a dispersing agent, 10-20 parts of silica nanoparticles, 10-20 parts of titanium dioxide nanoparticles, 60-120 parts of polyurethane, 100-200 parts of acrylic resin, 5-7 parts of a cross-linking agent and 2-5 parts of a penetrant, and then cooling the mixture to form glue; S2: dipping printing paper into the glue, and then drying the glue on the surfaces of the printing paper. By coating the surfaces of the printing paper with mixture coatings of the alumina powder, the silica nanoparticles and the titanium dioxide nanoparticles, the mixture coatings are wear-resistant, hydrophobic and oleophobic, increase the wear resistance of the decorative paper so that the decorative paper is less prone to wear, and increase dust resistance of the decorative paper itself to reduce the number of times of wiping and to prolong the service lifetime of the decorative paper.