The invention provides an RFID technology based concrete quality monitoring system and a working method thereof. The system comprises a production information monitoring unit, a supplier inputting unit, a constructor detecting unit and a central monitor control unit. The working method comprises the following steps: electronic tag initialization, production information monitoring and early warning, supplier information inputting, constructor detecting, etc. The invention can track and manage the whole process of concrete, including production, vehicle transport, unloading detection, construction site detection, maintenance and the like, and efficiently monitor the concrete quality.