A process to perform a controlled exothermic delignification of
biomass, said process comprising the steps of: - providing a
system comprising at least a first vessel and a second vessel; - providing a
biomass comprising
lignin,
hemicellulose and
cellulose fibers into said first vessel; - providing an aqueous acidic composition comprising an acid selected from the group consisting of:
sulfuric acid; an alkylsulfonic acid; an arylsulfonic acid and combinations thereof; - providing a modifier component; - providing a
peroxide component; - exposing said
biomass to said
sulfuric acid, modifier and
peroxide components, creating a reaction
mass; - mixing said reaction
mass; - allowing said
sulfuric acid component and
peroxide component to come into contact with said biomass for a period of time sufficient to a delignification reaction to occur and remove a pre-determined amount of said
lignin from said biomass; wherein said pre-determined amount is assessed by determining a first remaining peroxide concentration in the reaction
mass, with a suitable apparatus, when said first remaining peroxide concentration is reached, the biomass is transferred to said second vessel.