The invention discloses a method for degrading
organic dye through a
metal organic framework film based on metalloporphyrin. The method is characterized in that the
porphyrin metal organic framework film is generated on the surface of a transparent
glass sheet and placed on a net-shaped support to be hung in an
organic dye solution, and
irradiation is performed for 1-4 h with the visible
light intensity of 300 W at indoor temperature so that the
organic dye solution can be degraded to the concentration at which the organic dye solution can be discharged. The preparation process of the
metal organic framework film based on metalloporphyrin is characterized in that the transparent
glass sheet pretreated with 3-APTMS is reacted with (4-carboxyphenyl)
manganese(iron /
cobalt)
porphyrin, a solution containing Zn2+ and 2,2'-dimethyl-4,4'-
bipyridine in a
steeping mode, a product is washed with
solvent after one time of
steeping circulation is completed, the
steeping step is repeated, and the thickness of the film is controlled by the number of steeping circulation times, so that the oriented, ordered and porous
porphyrin metal organic framework film is prepared. According to the method, the
metal organic framework film is used for performing light degradation on a single or
mixed solution formed by
methylene blue,
methyl orange and
rhodamine, is good in
catalytic effect and convenient to recycle, and is a replaceable good novel material used for degrading organic dye.