The invention relates to the technical field of photocatalytic
hydrogen evolution, in particular to a preparation method and application of an MOF-derived In2S3 / ZnIn2S4
composite material for photocatalytic
hydrogen evolution, and the preparation method comprises the following steps: S1, preparation of an MIL-68 precursor, S2, preparation of In2O3, and S3, preparation of the In2S3 / ZnIn2S4
composite material. The preparation operation process of the In2S3 / ZnIn2S4
composite material disclosed by the invention is simple, and the simultaneous generation of In2S3 and the ultrathin
nanosheet In2S3 / ZnIn2S4 is successfully realized; a
heterojunction structure is constructed between the n2S3 and the ZnIn2S4; the
heterojunction has unique structural characteristics, and the photocatalytic
hydrogen evolution activity is effectively improved through the synergistic effect of a built-in
electric field, electrons and an interface structure; the MOF morphology is reserved, so that the In2S3 / ZnIn2S4 has high
porosity, the ZnIn2S4 thin nanosheets shorten the charge
diffusion path of light holes in water, sufficient light absorption is ensured, and more catalytic activity centers are exposed; and the prepared
metal organic framework derived In2S3 / ZnIn2S4 composite material has excellent performance
advantage in the field of photocatalytic
hydrogen evolution.