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31results about How to "Delayed softening and shedding" patented technology

Electrode active material for lead-acid storage battery

The invention discloses an electrode active material for a lead-acid storage battery. The electrode active material comprises lead powder and a non-metallic titanium compound; the lead powder comprises one or more kinds of metal lead powder, ball-milling lead powder, Barton lead powder, Pb<2>O powder, PbO powder, Pb<2>O<3> powder, Pb<3>O<4> powder and PbO<2> powder; and the non-metallic titanium compound comprises one or more kinds of titanium sulfide, titanium nitride, titanium boride, titanium carbide, titanium hydride, titanium hydroxide, titanium silicide, a symbiotic blend of the abovementioned compounds on an atomic micro level or atomic cluster level, and doped compounds formed by doping the abovementioned compounds with one or more kinds of F, Sb, Sn, Ca, Bi, Co, Ca, Al, Mg, N, P, O and C. By virtue of the electrode active material for the lead-acid storage battery with an improved formula, the specific power, specific energy, charging-discharging efficiency, cycle life, low-temperature performance and the like of the lead-acid storage battery can be obviously improved.
Owner:杨春晓

Negative lead paste for lead-carbon battery

The invention provides a negative lead paste for a lead-carbon battery. The negative lead paste is prepared from the following components in parts by weight: 1-99 parts of lead powder, 0.1-90 parts of a carbon-oxide composite material, 0-0.5 part of carbon black, 0.1-2 parts of barium sulfate, 0.05-0.1 part of a short fiber and 0.01-3.2 parts of an organic swelling agent. Oxides on the surface and in holes of the carbon material of the lead paste are tightly adsorbed to the periphery of the carbon material in an ionic form, and are recombined on the surface and in the holes of the carbon material in curing and drying processes; and a tiny oxide film is evenly attached to the active surface and the holes of the carbon material by 'dissolving and recombination', so that the bonding degree of the carbon material and the oxides is greatly improved; the conduction characteristics and the capacitance characteristics of the carbon material are put into a fully play; and hydrogen evolution on the surface of the carbon material is limited.
Owner:CHINA ELECTRIC POWER RES INST +3

Electrode active material for lead-acid storage battery

InactiveCN106876667AHigh porosityInhibition of agglomeration and cloggingLead-acid accumulatorsCell electrodesSpecific energyMixed type
The invention discloses an electrode active material for a lead-acid storage battery. The electrode active material comprises lead powder and composite material granules; the lead powder comprises one or more kinds of metal lead powder, ball-milling lead powder, Barton lead powder, Pb<2>O powder, PbO powder, Pb<2>O<3> powder, Pb<3>O<4> powder and PbO<2> powder; and the composite material granules comprise one or more kinds of coating type composite material granules and mixed type composite material granules. By virtue of the electrode active material for the lead-acid storage battery with an improved formula, the specific power, specific energy, active material utilization rate, charging-discharging efficiency, cycle life, low-temperature performance and the like of the applied lead-acid storage battery can be obviously improved.
Owner:杨春晓

Maintenance-free starting lead-acid storage battery with long service life and high specific energy, and production method thereof

The invention relates to a long-service-life high-specific-energy maintenance-free starting lead-acid storage battery and a production method thereof. According to the battery, lead plasters coated atthe upper portion and the lower portion of a grid of at least one of a positive electrode plate and a negative electrode plate are different, and the conductivity or the utilization rate of the leadplaster at the lower portion of the grid is superior to that of the lead plaster at the upper portion of the grid. According to the invention, the upper portion and the lower portion of an electrode plate adopt different formulas and are respectively coated and filled, wherein the acid content of the lead plaster at the lower portion is different so as to reduce that the apparent density of the lead plaster or the conductive substance content of the lead plaster at the lower portion is different so as to improve the utilization rate, so that the problem of low utilization rate of the active substance at the lower portion is effectively improved, and the capacity of the battery is improved; the internal resistance of the lower portion is reduced, and the utilization rate is improved, so that the problem of high proportion of upper discharge capacity is slowed down, wherein the upper discharge capacity of the electrode plate is reduced and the discharge rate is reduced under the condition of the same discharge capacity, so that the softening and falling of the active substance are reduced, and the service life of the battery is prolonged; and under the condition of the same paste coating amount, the capacity, the low-temperature discharge performance and the cycle durability of the prepared battery are improved.
Owner:CAMEL GRP HUAZHONG BATTERY

Long-life lead acid secondary battery

The invention discloses a long-life lead acid secondary battery and intends to provide a long-life lead-acid battery which can effectively improve the problem of negative electrode vulcanization and reduce the occurrence of the negative electrode vulcanization failure, so as to effectively prolong the charging and discharging cycle life of the lead acid secondary battery. The long-life lead acid secondary battery comprises an electrode group, which comprises a plurality of positive and negative plates. The negative plates comprises a negative grid, which comprises a grid inner core made of highly conductive metal and a lead or lead alloy cladding layer cladding the surface of the grid inner core.
Owner:CHAOWEI POWER CO LTD

Positive plate reinforced lead-acid accumulator

The invention discloses a positive plate reinforced lead-acid accumulator which comprises a positive plate and a negative plate. The invention is characterized in that a carbon fiber composite coating is coated on the active substance surface of the positive plate, and the carbon fiber composite coating is the mixture of carbon fibers and the corresponding substrate. Since the carbon fiber composite coating with high strength and superhigh bearing capacity is coated on the active substance surface of the positive plate, the invention greatly enhances the structural strength and the dimensional stability of the positive plate and prolongs the service life of the accumulator.
Owner:SUZHOU UNIV

Composite additive of lead-acid storage battery

The invention discloses a composite additive of a lead-acid storage battery, The composite additive is used for being added in a lead plaster of a positive pole of the lead-acid storage battery. The composite additive comprises the components in percentage by mass: 0.15-0.3% of graphite, 0.5-1.5% of 4BS (tetrabasic lead sulfate), 0.1-0.7% of silicon dioxide, 0.05-0.1% of antimony trioxide, and 0.05-0.15% of stannous sulfate, wherein the content is mass proportion of the components to lead powder. According to the composite additive of the lead-acid storage battery, the consistency of a battery pack is beneficially improved, the softening and falling of active substances can be reduced, and further the service life of the battery pack can be prolonged.
Owner:TIANNENG BATTERY WUHU

High-magnification lead storage battery for communication

The invention discloses a high-magnification lead storage battery for communication. The high-magnification lead storage battery comprises a positive plate, a negative plate and an electrolyte; the lead plaster of the positive plate comprises, by weight, 1000 parts of lead powder, 30-50 parts of red lead, 0.5-1.0 part of silver-plated carbon fiber, 2.0-3.0 parts of expanded graphite, 8-10 parts ofsodium bicarbonate, 1.5-2.0 parts of magnesium silicate, 0.3-0.5 part of bismuth oxide, 1.5-2.0 parts of a Teflon solution, 110-120 parts of sulfuric acid with the density of 1.40 g / ml and 100-110 parts of deionized water; the lead plaster of negative plate comprises, by weight, 1000 parts of the lead powder, 1.0-1.5 parts of silver-plated carbon fiber, 2.5-3.0 parts of acetylene carbon black, 12-15 parts of ultrafine barium sulfate, 2.5-4.0 parts of lignin, 1.0-2.0 parts of humic acid, 2.5-5.0 parts of carbon nanotube slurry, 0.5-1.0 part of polyester fiber, 90-110 parts of sulfuric acid with the density of 1.40 g / ml and 100-110 parts of deionized water; and anhydrous sodium sulfate and stannous sulfate are added into the electrolyte. The cycle life of the lead storage battery is two times or more that of a conventional lead storage battery.
Owner:TIANNENG BATTERY GROUP

Lead mesh grid for lead storage battery and preparation method of lead mesh grid

The invention discloses a lead mesh grid for a lead storage battery and a preparation method of the lead mesh grid. The lead mesh grid is characterized by comprising a grid body formed by weaving warps and wefts, wherein the grid body at least comprises one independent grid; a lead mesh coating area formed by the grid body is arranged at the boundary of the independent grid, and thick plastic wires or thick lead wires are arranged in the weft direction of the grid body so as to form two side frames extending in the weft direction of the independent grid; and a lead mesh coating area formed bythe grid body is arranged at the boundary of the independent grid, and thick plastic wires or thick lead wires or a plurality of thin plastic wire twisted edges or hot melting wire twisted edges are arranged in the warp direction of the grid body so as to form two side frames extending in the warp direction of the independent grid. The lead mesh grid has the advantages that the use amount of leadis small, the grid is provided with the side frames, expansion of active substances can be limited in the charging and discharging process of the battery, positive and negative active substance contact short circuit and positive active substance softening and falling are not likely to happen, the service life of the battery is prolonged, and the grid is provided with tabs and does not need prefabricated busbars.
Owner:CHAOWEI POWER CO LTD

High-energy-density zinc-nickel battery positive electrode manufacturing method

The invention belongs to the technical field of zinc-nickel batteries. The invention discloses a high-energy-density zinc-nickel battery positive electrode manufacturing method. The method comprises:adding a thickner to a raw material A, mixing uniformly, to obtain a slurry A, dissolving a divalent nickel compound in water to obtain an aqueous solution, adding the slurry A and a surfactant, stirring and treating to obtain a slurry B, adding polytetrafluoroethylene to the slurry B, to prepare a positive electrode slurry, putting a positive electrode matrix into the positive electrode slurry until the positive electrode matrix is completely submerged, and then taking the positive electrode matrix out after a period, preparing a battery positive electrode piece, and performing aftertreatmentto obtain a high-energy-density zinc-nickel battery positive electrode. The method can solve a problem that high-energy-density zinc-nickel battery positive electrode active materials are not tightlycombined, and can reduce softening and shedding of the positive electrode active materials, reduce internal resistance, improve utilization ratio of the active materials, improve charging acceptanceof the electrode, and improve battery capacity, cycle life and charge and discharge conversion efficiency, to prevent early decay of battery capacity.
Owner:CHAOWEI POWER CO LTD

Enhanced positive plate of power lead-acid storage battery

The invention discloses an enhanced positive plate of a power lead-acid storage battery. The positive plate comprises a positive plate grid. The positive plate is characterized in that a carbon fiber powder layer is sprayed and pressed on the active substance surface of the positive plate; since the positive plate of the battery is formed by spraying and pressing a carbon fiber powder layer on the active substance of the positive pole, the carbon fiber powder has higher specific strength and specific modulus, and each constituent of the carbon fiber dose not participate in the electrochemical reaction of the battery in the charging or discharging process of the battery, the positive plate has higher strength, high and strong carrying capacity and stronger creep deformation resistance, thus the structure strength and the size stability of the positive plate can be improved greatly, the active substance of the positive pole is not easy to soften and fall off, and the service life of the lead-acid storage battery can be prolonged consequentially.
Owner:SUZHOU UNIV

Acid-free external formation method of lead-acid storage battery and lead-acid storage battery

The invention provides an acid-free external formation method of a lead-acid storage battery and the lead-acid storage battery. During formation, a sulfuric acid electrolyte is substituted by a neutral electrolyte, acid mist pollution is prevented, and lead-containing wastewater generated during washing of the traditional external formation pole plate is avoided; meanwhile, the formation efficiency and the pole plate quality are superior to those of an internal formation process; and moreover, no waste acid is generated like the internal formation process, and the purposes of saving energy, reducing emission and also improving product quality are achieved.
Owner:江西力之奇新能源科技有限公司

Long-life silicon-based bipolar lead storage battery positive electrode lead paste and preparation method thereof

The invention discloses a long-life silicon-based bipolar lead storage battery positive electrode lead paste and a preparation method thereof. The positive electrode lead paste formula comprises the following components: lead powder, short fibers, graphite powder, SnSO4, Ti4O7, Sb2O3, 4PbO.PbSO4, sodium perborate, dilute sulfuric acid and deionized water. The preparation method comprises the steps: S1, uniformly dispersing graphite powder, 4PbO.PbSO4, SnSO4, Ti4O7, Sb2O3, sodium perborate materials and the short fibers into lead powder during preparation of lead paste, and carrying out dry stirring for 5 minutes until the materials are uniformly mixed, so as to prepare a premix 1; S2, quickly adding deionized water into the premix 1, and stirring for 10 minutes until the deionized water and the premix 1 are uniformly mixed, so as to obtain a premix 2; S3, slowly adding dilute sulfuric acid into the premix 2, controlling the adding time to be 10 min and the mixing temperature to be 70 DEG C, continuously stirring for 10 min, cooling to 50 DEG C, measuring the apparent density, and controlling the apparent density to be 4.45+ / -0.1 g / cm<3>. According to the invention, the electric conductivity of the lead paste can be obviously improved, the softening and falling of the lead paste can be effectively delayed, and the cycle life cycle is prolonged.
Owner:ANHUI LEOCH POWER SUPPLY

Lead-calcium formation colloid electrolyte

The invention discloses a lead-calcium formation colloid electrolyte which is composed of the following components in percentage by weight: 0.8-5% of gas-phase silicon dioxide, 0.1-2% of sodium silicate, 1-2% of anhydrous sodium sulfate, 0.1-0.5% of stannous sulfate, 0.05-0.5% of sodium carboxymethyl cellulose, 0.02-0.5% of bismuth trioxide, 0.2-3% of phosphoric acid, 28-38% of sulfuric acid and the balance of water. When being used for preparing a lead-calcium formation battery, the colloid electrolyte improves the early capacity attenuation effect of the lead-calcium formation battery, decelerates the softening shedding of the active substances at the positive pole, and prolongs the deep cycle service life of the battery.
Owner:江苏海宝电池科技有限公司

Lead acid storage battery positive electrode lead paste containing calcium plumbate

The invention relates to the field of the lead acid storage battery, and discloses lead acid storage battery positive electrode lead paste containing calcium plumbate. The ingredients of the lead paste are as follows based on mass percentage: 71-89% of lead powder, 4-14% of sulfuric acid, 5-18% of water, 0.05-2% of short fibers and 0.5-5% of CaPbO3. The lead acid storage battery positive electrode lead paste provided by the invention can improve the formation efficiency, reduce softening and falling off of positive electrode active substances, improve the cold starting performance, improve the discharge capacity of the battery, and prolong the service life of the battery.
Owner:CHAOWEI POWER CO LTD

Lead mesh grid for lead storage battery and preparation method thereof

The invention relates to a lead mesh grid for a lead storage battery. The lead mesh grid comprises a grid body formed by weaving warps and wefts, and the grid body at least comprises an independent grid. The coarse plastic weft frames are formed at the two sides in the weft direction of the independent grids, coarse lead wire wefts are arranged between the coarse plastic weft frames, and the fineplastic wefts are arranged between the coarse lead wire wefts. The coarse plastic warp frames are formed at the two sides in the warp direction of the independent grids, and fine plastic warps are arranged between the thick plastic warp frames. The lead mesh grid has the advantages that the use amount of lead is small; the grid is provided with the frame, so that the expansion of active substancescan be limited in the charging and discharging process of the battery, and the positive and negative active substance contact short circuit and positive active substance softening and falling are notlikely to happen; the service life of the battery is prolonged; and the grid is provided with tabs without the prefabricated busbars.
Owner:CHAOWEI POWER CO LTD

A kind of lead-acid storage battery cathode lead paste containing calcium lead acid

The invention relates to the field of the lead acid storage battery, and discloses lead acid storage battery positive electrode lead paste containing calcium plumbate. The ingredients of the lead paste are as follows based on mass percentage: 71-89% of lead powder, 4-14% of sulfuric acid, 5-18% of water, 0.05-2% of short fibers and 0.5-5% of CaPbO3. The lead acid storage battery positive electrode lead paste provided by the invention can improve the formation efficiency, reduce softening and falling off of positive electrode active substances, improve the cold starting performance, improve the discharge capacity of the battery, and prolong the service life of the battery.
Owner:CHAOWEI POWER CO LTD

A kind of preparation method of positive electrode of zinc-nickel battery with high specific energy

The invention belongs to the technical field of zinc-nickel batteries. The invention discloses a method for preparing a positive electrode of a high specific energy zinc-nickel battery, which comprises uniformly mixing raw material A and a thickener to prepare a slurry A, dissolving a divalent nickel compound in water to prepare an aqueous solution, adding the slurry A and Surfactant, stirring treatment to prepare slurry B, adding polytetrafluoroethylene to slurry B to prepare positive electrode slurry, putting the positive electrode base into the positive electrode slurry until it is completely submerged, taking it out after standing for a period of time, and making The positive electrode sheet of the battery is obtained, and the positive electrode of the zinc-nickel battery with high specific energy is obtained through post-processing. The invention can solve the problem that the positive electrode active materials of the high specific energy zinc-nickel battery are not tightly bonded, can reduce the softening and falling off of the positive electrode active material, can reduce internal resistance, improve the utilization rate of the active material, improve the charging acceptance capacity of the electrode, increase the battery capacity, Cycle life and charge-discharge conversion efficiency avoid early decay of battery capacity.
Owner:CHAOWEI POWER CO LTD

A kind of internalization of lead calcium into colloidal electrolyte

The invention discloses a lead-calcium formation colloid electrolyte which is composed of the following components in percentage by weight: 0.8-5% of gas-phase silicon dioxide, 0.1-2% of sodium silicate, 1-2% of anhydrous sodium sulfate, 0.1-0.5% of stannous sulfate, 0.05-0.5% of sodium carboxymethyl cellulose, 0.02-0.5% of bismuth trioxide, 0.2-3% of phosphoric acid, 28-38% of sulfuric acid and the balance of water. When being used for preparing a lead-calcium formation battery, the colloid electrolyte improves the early capacity attenuation effect of the lead-calcium formation battery, decelerates the softening shedding of the active substances at the positive pole, and prolongs the deep cycle service life of the battery.
Owner:江苏海宝电池科技有限公司

A kind of lead-calcium internalization into colloidal electrolyte and preparation method thereof

The invention discloses a lead-calcium formation colloid electrolyte which is composed of the following components in percentage by weight: 0.8-5% of gas-phase silicon dioxide, 0.1-2% of sodium silicate, 1-2% of anhydrous sodium sulfate, 0.1-0.5% of stannous sulfate, 0.05-0.5% of sodium carboxymethyl cellulose, 0.02-0.5% of bismuth trioxide, 0.2-3% of phosphoric acid, 28-38% of sulfuric acid and the balance of water. The invention also discloses a preparation method of the lead-calcium formation colloid electrolyte. When being used for preparing a lead-calcium formation battery, the colloid electrolyte improves the early capacity attenuation effect of the lead-calcium formation battery, decelerates the softening shedding of the active substances at the positive pole, and prolongs the deep cycle service life of the battery. The colloid electrolyte disclosed by the invention has the advantages of favorable consistency, favorable colloid thixotropy and favorable colloid stability.
Owner:江苏海宝电池科技有限公司

Positive plate of lead-acid accumulator

The invention discloses a positive plate of a lead-acid accumulator, which comprises a positive grid and is characterized in that the surface of the positive grid is coated with a carbon fiber compound substrate prepared by the mixture of carbon fiber and a corresponding matrix. The carbon fiber compound basement layer is coated with positive active materials prepared by lead ointment. A mixture comprising the components by weight of 10%-40% of carbon fiber, 10%-40% of graphite fiber, 10%-40% of anisotropic graphite, 5%-20% of carboxymethylcellulose and 10%-30% of polytetrafluoroethylene is prepared into a paste slurry to be coated on the surface of the positive grid and then is dried and cured to form the carbon fiber compound basement layer. As a carbon fiber compound substrate with high strength and high carrying capacity is coated on the positive grid, the invention enhances the structural strength of the positive plate, the dimensional stabilityand the creep resistance of the positive grid, thus greatly prolonging service life of the lead-acid accumulator.
Owner:SUZHOU UNIV

Enhanced power lead-acid battery positive plate

The invention discloses an enhanced positive plate of a power lead-acid storage battery. The positive plate comprises a positive plate grid. The positive plate is characterized in that a carbon fiber powder layer is sprayed and pressed on the active substance surface of the positive plate; since the positive plate of the battery is formed by spraying and pressing a carbon fiber powder layer on the active substance of the positive pole, the carbon fiber powder has higher specific strength and specific modulus, and each constituent of the carbon fiber dose not participate in the electrochemical reaction of the battery in the charging or discharging process of the battery, the positive plate has higher strength, high and strong carrying capacity and stronger creep deformation resistance, thus the structure strength and the size stability of the positive plate can be improved greatly, the active substance of the positive pole is not easy to soften and fall off, and the service life of the lead-acid storage battery can be prolonged consequentially.
Owner:SUZHOU UNIV

Lead paste for battery positive plate and preparation method of lead paste and positive plate

The invention provides lead paste for a battery positive plate and a preparation method of the lead paste and the positive plate. The lead paste for the battery positive plate comprises the following raw material components: lead powder, red lead powder, a mixture of tetrabasic lead sulfate and metal oxide, sulfuric acid, water and modified silicon; the modified silicon powder is added while the mixture of the tetrabasic lead sulfate and the metal oxide is added into the formula of the lead plaster, so that the growth of tetrabasic lead sulfate crystals is promoted; the crystal size of the crystals is further influenced by the addition of the modified silicon powder, the crystal size is finer and more uniform, the cohesiveness between the lead plaster is better, the adhesion force and coating capacity are better, and the problem that the lead paste is dispersed after tetrabasic lead sulfate is independently added and the problem that the lead paste is sticky after modified silicon powder is independently added are solved; and through simultaneous adding and use, crystals which are regular, fine and uniform in size are formed, and the paste mixing and plate coating technological performance is improved.
Owner:浙江埃登达新能源材料有限公司

A kind of negative electrode of lead-carbon battery

The invention provides a lead-carbon battery negative electrode. The negative electrode comprises the following components in parts by mass: 85-115 parts by mass of lead powder; 0.5-15 parts of metal oxide; 0.1-40 parts of carbon material; 9-12 parts of sulfuric acid; 0.2-3 parts of barium sulfate; Sodium lignosulfonate 0-2.5; humic acid 0.1-3; short fiber 0.05-1, water 14-16, barium stearate 0.18-0.25. The negative electrode of the lead-carbon battery applies the composite material of heteroatom-doped zero-dimensional carbon material and one-dimensional carbon nano-conductive agent to the lead paste additive of the negative electrode of the lead-carbon battery, forming a three-dimensional network in the negative electrode, which can reduce the use of carbon materials. Increase the conductivity of the negative electrode of the battery and the utilization rate of the active material, and improve the charge acceptance and specific power of the lead-acid battery.
Owner:CHINA ELECTRIC POWER RES INST +2

Method for repairing positive active material of lead-acid battery

The invention relates to a method for repairing a positive active material of a lead-acid battery, and belongs to the technical field of lead-acid storage batteries. The method comprises the following steps: (1) carrying out low-current complete discharge on a lead-acid battery to be repaired; (2) taking out the positive pole group, forming a transition battery with the auxiliary pole group, filling sulfuric acid for electrolysis, and charging; (3) taking out the positive electrode group, washing with water, putting into a constant-temperature box, and carrying out slow oxidation treatment; (4) recombining the plate group and the auxiliary plate group into a transition battery, pouring a sodium sulfate solution, standing and then charging; and (5) taking out the positive electrode group, washing with water, drying, combining the dried positive electrode group with the negative electrode group of the primary battery, putting into the original battery jar, and pouring a sulfuric acid electrolyte for charging. The method is scientific and reasonable in design, does not need to add other additives, fundamentally slows down the crystallization process of the positive active material lead dioxide, inhibits softening and falling off and performance reduction of the active material, and obviously prolongs the cycle service life of the lead-acid battery.
Owner:ZIBO TORCH ENERGY
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