The invention discloses a novel common mode rejection balun structure for a magnetic resonance radio frequency coil. The structure comprises an upper layer structure, a middle layer structure and a lower layer structure, wherein the upper layer is a solenoid formed by winding a coaxial line, the middle layer is a hard printed circuit board, and the lower layer is a double-layer flexible printed circuit board; the double-layer flexible printed circuit board comprises a base material, an upper-layer conductor located on an upper surface of the base material and a lower-layer conductor located on a lower surface of the flexible base material; the upper-layer conductor and the lower-layer conductor are partially overlapped, and the overlapped upper-layer conductor, the overlapped lower-layer conductor and the base material between the upper-layer conductor and the lower-layer conductor form a planar flexible capacitor, shielding layers at two ends of the solenoid are respectively welded on the hard printed circuit board, and are connected in parallel with the planar flexible capacitor sequentially through the copper-clad layer conductor on the hard printed circuit board, the connecting wire conductor and the conductor on the flexible printed circuit board. According to the novel common-mode rejection balun structure for the magnetic resonance radio frequency coil, the size and the weight are obviously smaller than those of an existing common-mode rejection balun, frequency adjustment is very convenient, and the cost is lower.