The invention belongs to the field of chiral
silicon synthesis, and discloses a
silicon-center chiral
silicon-
oxygen compound. The compound has a structure represented by general formula I shown in the specification. In the formula I, X is Si(R<3>)n or a formula also shown in the specification, R<1> is selected from
alkyl, cycloalkyl and
aryl, R<2> is selected from
alkyl, substituted phenyl and
aryl, R<3> is selected from
alkyl, phenyl and substituted phenyl, n is 3, the three R<3> are the same or different, R<4> is selected from
hydrogen and (C1-C4) alkyl, m is selected from 0, 1, 2 and 3, and Y is selected from substituted phenyl, substituted pyrenyl,
aryl, heteroaryl and cycloalkyl. The invention also discloses a preparation method of the compound. Various highly functionalized chiral siloxanes and silyl ethers are obtained with good chemical, regional and stereo control and high yield, the variety of silicon center chiral compounds is expanded, and the method has the advantages of high enantioselectivity, wide substrate application range, mild
reaction conditions,
atom economy and the like. In addition, the compound provided by the invention has a huge application prospect in chiral organic photoelectric materials.