The invention discloses a highly connected coordination polymer and a preparation method thereof. The highly connected coordination polymer adopts the following chemical formula: [Zn5(3,3'-tmbpt)(btec)2(OH)2], wherein betc is deprotonated 1,2,4,5-pyromellitic acid; 3,3'-tmbpt is 1-((1H-1,2,4-triazole)methyl)-3,5-bis(3-pyridyl)-1,2,4-triazole. Carboxyl groups of polycarboxylic acid anions can coordinate with metal ions to form metal clusters with larger size; the metal clusters serve as nodes, so that connections of the nodes can be greatly increased. In addition, distances among several coordinating groups of a polydentate nitrogen-containing ligand 3,3'-tmbpt is relatively large, so that steric hindrance is relatively small during coordination, and the metal clusters can further expand easily to form the coordination polymer adopting highly connected structure. The coordination polymer can serve as a broadband semiconductor material and a molecular-based light emitting material to be further developed and applied.