The invention relates to a comprehensive utilization method of an ionic membrane electrolytic
saline solution waste liquid, which comprises the step of sending dechlorinated dilute brine
coming out of an electrolytic tank to a membrane process denitration device for denitration. The comprehensive utilization method is characterized by comprising the following steps of: pre-adjusting the pH value of a
system to 3-8 by using a
saline solution PH value
automatic control device, exchanging the heat till the temperature of the
system is 25-50 DEG C, removing free
chlorine till the content of
chlorine is less than or equal to 3 ppm, sending into a primary membrane
separation system for primary membrane separation and controlling the primary membrane separation pressure to be not higher than 3.0 MPa; and then sending into a secondary membrane
separation system for secondary membrane separation, controlling the secondary membrane separation pressure to be not higher than 3.5 MPa, separating to obtain desulfurized brine and concentrated
nitrate water, sending the dissolved desulfurized brine to an ionic membrane electrolytic
saline solution device for reutilization and sending the concentrated
nitrate water to a thermal method denitration device to prepare
thenardite. The invention has the beneficial effects that as the two stages of membrane separation systems are adopted, the pressure is more stable, the membrane service life is long, and the separation effect is good; the content of
sodium sulfate in the separated concentrated
nitrate water can reach above 90 g / l, and the content of
sodium sulfate in the desulfurized brine can reach below 3 g / l.