The invention discloses a high-stability PA66 modified material and a preparation method thereof. The modified material consists of the following components in percentage by weight: 65-76 percent of PA66 resin, 10-15 percent of PA6 resin, 2 percent of anti-wear agent, 1.5 percent of composite lubricating agent, 0.3 percent of antioxidant, 10-15 percent of wollastonite in powder, 0.1 percent of talc powder and 0.3 percent of coupling agent. The invention further provides a preparation method of the modified material. By blending the anti-wear agent and the wollastonite in powder and modifying PA66, the prepared nylon material has high mechanical property and high wear resistance, the defect of easy moisture absorption of nylon is overcome, and the size is stable. The high-stability PA66 modified material can be widely applied to the fields of gears, bearings, fan blades, bicycle parts, automobile industry parts, electronics and electrics, precision engineering products, mechanical treatment, sports apparatuses and the like.