The invention provides a composite
silicon-carbon
electrode material with a shelly structure. The composite
silicon-carbon
electrode material is composed of reduced
graphene oxide,
silicon nanoparticles and carbon nanotubes, wherein the silicon nanoparticles are dispersed among multiple
layers of the reduced
graphene oxide; gaps are left between the silicon nanoparticles and the reduced
graphene oxide; and the carbon nanotubes prop open the reduced graphene oxide and allow the reduced graphene oxide to include the silicon nanoparticles like shells. The invention also provides preparation and application of the composite silicon-carbon
electrode material with the shelly structure. According to the invention, the shelly structure is formed among the
layers of the reduced graphene oxide, thecarbon nanotubes provides support among the
layers of the reduced graphene oxide and
spatial partition for the silicon nanoparticles, so reserved space is left for the
volume expansion of silicon during charging and discharging of a battery, and the
structural integrity of an active material of a negative electrode can be better maintained; and thus, the battery is allowed to have high capacity which is hard to attenuate, good cyclicity and long service life.