The invention relates to a novel multi-stable ultrasonic detection sensor which is used in the field of ultrasonic detection and includes: an acoustic resistance matching layer, a metal electrode, a piezoelectric film, a high-voltage-resistant insulating layer, a hollow chamber sealing layer, a back lining layer, and an electromechanical control circuit board. The ultrasonic detection sensor can achieve a multi-stable working mode of combination of piezoelectric ultrasonic sensing and capacitive ultrasonic sensing on one ultrasonic transducer unit through the electromechanical control circuit board, wherein each stable working mode can be designed according to optional ultrasonic frequencies, for example, a design scheme of capacitive low frequency ultrasonic sensing and piezoelectric high frequency ultrasonic sensing, thus considering both the depth and resolution of ultrasonic detection. The multi-stable ultrasonic detection sensor can be flexibly applied in ultrasonic detection on gas-phase, liquid-phase and solid-phase mediums, is simple in resistance matching, is small in size and is easy to integrate, can be produced in large scale and is low in cost, and has application prospects in the fields of underwater acoustic detection, bio-medical imaging, industrial ultrasonic non-destructive testing, etc.