The invention discloses a potassium superoxide air regenerating device for emergent risk avoiding under coal mines, which comprises a device main body, wherein the device main body adopts a hollow cavity structure; the device main body comprises an air inlet area, a reaction area and an air discharge area from the bottom up sequentially; a lower air permeable diaphragm is arranged between the air inlet area and the reaction area; the reaction area is divided into an upper cavity, a middle cavity and a lower cavity; middle air permeable diaphragms are arranged between the three cavities; and each of the upper cavity, the middle cavity and the lower cavity is provided with a potassium superoxide reactor inside. The potassium superoxide air regenerating device is perfect and reasonable in structure, convenient in use and easy to maintain; the device requires no power when working; no substance harmful to human and the environment is generated during the working process and after the reaction is terminated; and while CO2 is eliminated, harmful gases such as CH4, CO, H2S, SO2, NOX and the like are absorbed and cleansed. The potassium superoxide air regenerating device provided by the invention is controllable and can be used for continuously supplying oxygen to airtight space.