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229results about How to "Excellent electromagnetic wave absorption performance" patented technology

Preparation method of MXene/cellulose composite aerogel

The invention relates to the field of aerogel and electromagnetic absorbing materials, in particular to a preparation method of MXene/cellulose composite aerogel. The preparation method includes the steps that firstly, MAX phase ceramic powder is added into a mixed water solution of lithium fluoride, hydrochloric acid and hydrofluoric acid in a certain proportion for etching to obtain MXene nano-powder; a cellulose sol method is adopted, cellulose powder is added into a mixed water solution of sodium hydroxide and urea in a certain proportion, and a transparent cellulose mixed solution is prepared by cooling the mixture to -12 DEG C; the temperature is maintained, the MXene nano-powder is added into the cellulose mixed solution, and then the appropriate amount of epichlorohydrin is added to the mixture and the mixture is stirred thoroughly for chemical crosslinking; the temperature is raised, and the obtained homogeneous mixture is subjected to a gel reaction; and a gel product is frozen directionally and then freeze-dried to obtain the MXene/cellulose composite aerogel. The composite aerogel has the characteristics of low density, high porosity, good absorbing performance, wide absorbing frequency band and the like, and is convenient to use and suitable for large-scale application in the aerospace field.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Graphene aerogel and preparation method and application thereof

The invention discloses a graphene aerogel and a preparation method and an application thereof, wherein the aerogel is prepared from the following method: (1) pre-reduction treatment: adding a reducing agent to a graphene oxide solution, mixing, carrying out ultrasonic dispersion, and carrying out pre-reduction treatment, to obtain a semi-reduction graphene hydrogel; (2) final reduction treatment:adding a reducing agent, carrying out ultrasonic treatment, and then carrying out final reduction treatment, to obtain a graphene hydrogel; and (3) acid / alkali soaking: placing the graphene hydrogelin an acid or alkali aqueous solution, soaking, washing the hydrogel to be neutral, sucking out the excess liquid, and carrying out freeze drying, to obtain the graphene aerogel. The graphene aerogelis applied to electromagnetic wave absorption materials. The graphene aerogel obtained by the method has small density and good integrality, and has a certain mechanical strength and resillency; the prepared wave absorbing material has good electromagnetic wave absorption performance, and the wave absorbing performance can be adjusted; and the method has the advantages of simple process, short production cycle, low cost and good benefits, and is suitable for industrialized production.
Owner:苏州涤致良特种防护装备科技有限公司

Preparation method for carbon nano tube/ oxidized grapheme/ nanometer Fe3O4 sandwich hybrid wave absorbing thin films

This invention discloses a preparation method for carbon nano tubes / oxidized grapheme / nanometer Fe3O4 sandwich hybrid wave absorbing thin films, which solves the problem that the magnetism of the carbon nano tube is bad and the technical problem that solving the magnetism problem impacts the dispersibility of the carbon nano tube. The preparation method comprises steps of (1) preparing oxidized grapheme by using a Hummers method, 2) preparing oxidized grapheme- carbon nano tube water solution, 3) preparing nanometer Fe3O4 dispersion liquid,(4) utilizing a vacuum suction filter device to prepare hybrid sandwich thin films, picking half volume of the oxidized grapheme- carbon nano tube dispersion liquid, adding the dispersion liquid to an upper container of the vacuum suction filter device to perform vacuum suction filtration, adding the nanometer FE3O4 dispersion liquid to perform suction and filtration when the suction and filtration of the grapheme- carbon nano tube dispersion liquid is finished, and adding the residual grapheme- carbon nano tube dispersion liquid when the suction and filtration of the Nanometer Fe3O4 is almost finished, (5) placing the carbon nano tube / oxidized grapheme / nanometer Fe3O4 hybrid thin films along with the filtration films into two stainless steel dies for compacting, putting into a vacuum oven, curing for 2-8 hours at 200DEG temperature, and striping the filtration films after taking out.
Owner:SHENYANG AEROSPACE UNIVERSITY

Three-dimensional porous flower-like structure cobalt/carbon nano-composite electromagnetic wave absorbing material and preparation method thereof

The invention relates to a three-dimensional porous flower-like structure cobalt / carbon nano-composite electromagnetic wave absorbing material. Carbon in the electromagnetic wave absorbing material forms a three-dimensional skeleton in a flower-like structure, and carbon coated cobalt particles are uniformly distributed on a carbon matrix. The preparation method comprises the following steps: 1) serving divalent inorganic cobalt salt as a precursor of cobalt hydroxide, and dissolving the divalent inorganic cobalt salt and surfactant into a solvent according to a certain mass ratio; carrying out reaction under an enclosed condition, and after reaction, carrying out washing and drying on the product to obtain the cobalt hydroxide; carrying out calcination treatment on the prepared cobalt hydroxide to obtain cobaltosic oxide powders; and 2) mixing the cobaltosic oxide powders obtained in the step 1) with a carbon source, and carrying out reaction under an enclosed condition to obtain thethree-dimensional porous flower-like structure cobalt / carbon nano-composite electromagnetic wave absorbing material. The prepared electromagnetic wave absorbing material is high in saturation magnetization, high in coercive force, light in weigh and high in oxidation resistance and has an excellent electromagnetic wave absorption performance.
Owner:SHANDONG UNIV

Double-shell-structure carbonyl iron powder composite wave-absorbing material and preparation method thereof

The invention discloses a double-shell-structure carbonyl iron powder composite wave-absorbing material and a preparation method thereof, wherein the composite wave-absorbing material is of a double shell layer core-shell structure, the core is carbonyl iron powder, the inner layer of the double-shell layer is an insulating layer, and the outer layer of the double-shell layer is a magnetic layer;the thickness of the insulating layer is 1 nm-1 [mu] m; and the thickness of the magnetic layer is 1nm-5 [mu] m; the preparation method comprises the following steps: coating the surface of the carbonyl iron powder with the insulating layer and coating the surface of a core-shell structure precursor by a chemical coprecipitation method. The surface of the carbonyl iron powder is coated with the double-shell layer by the chemical coprecipitation method. The impedance matching characteristic of the material is greatly improved, meanwhile, a large amount of nano-interface heterojunction is formedat the interfaces of the inner core and the double-shell layer, so that interface polarization is effectively induced, the scattering effect is formed for electron migration, and electromagnetic waveloss mechanisms such as multi-reflection absorption, strong ] ferromagnetic resonance and eddy current loss and the like of the material are greatly improved, so that the wave absorbing performance of the material is remarkably improved; the composite wave-absorbing material is simple in preparation method, is uniform and compact in coating and controllable in coating layer thickness and particlesize.
Owner:CENT SOUTH UNIV

Electromagnetic-radiation-resistant protection film and preparation method thereof

The invention relates to the technical field of optical protection films, and especially relates to an electromagnetic-radiation-resistant protection film and a preparation method thereof. The preparation method comprises the following steps: step 1, preparing light-cure paint with electromagnetic radiation resistant function; step 2, coating a PET base material with the light-cured paint by using a slight-concave roller, and controlling the coating thickness of the light-cured paint to be 3-10 mu m, the diameter of the slight-concave roller to be 30-50 mm and the line screen of the slight-concave roller to be 40-400; step 3, curing the paint to obtain a film; and step 4, preparing the electromagnetic-radiation-resistant protection film. The electromagnetic-radiation-resistant protection film is good in electromagnetic-radiation-resistant effect, the technology is simple and manure and beneficial for popularization and application. When the electromagnetic-radiation-resistant protection film is used, the electromagnetic-radiation-resistant protection film can be attached to a handset or a display screen by tearing a PET protection film. Compared with electromagnetic-radiation-resistant equipment at home and abroad, such as radiation-proof clothes, electromagnetic-wave protection helmets and the like, the electromagnetic-radiation-resistant protection film is simple and convenient to use and easy to popularize.
Owner:NALI OPTICAL MATERIAL DONGGUAN

Three-dimensional porous sheet ferroferric oxide/carbon nanometer electromagnetic wave absorption material and preparing method thereof

The invention relates to a three-dimensional porous sheet ferroferric oxide/carbon nanometer electromagnetic wave absorption material and a preparing method thereof. Carbon in the electromagnetic waveabsorption material forms a three-dimensional framework of a flower-shaped structure, and ferroferric oxide particles wrapped by carbon are evenly distributed on a carbon base body. The preparing method includes the steps of firstly, making trivalent inorganic ferrite and urea as precursors for synthesizing ferroferric oxide dissolved together with a surface active agent in a solvent according toa certain mass ratio to have a reaction under closed conditions, washing and drying a product after the reaction is completed to prepare hydroxyl ferric oxide, and calcinating the prepared hydroxyl ferric oxide to obtain ferric oxide powder; secondly, mixing the ferric oxide powder in the first step with a carbon source to have a reaction under closed conditions to obtain the three-dimensional porous sheet ferroferric oxide/carbon nanometer electromagnetic wave absorption material. The electromagnetic wave absorption material is high in saturated magnetic susceptibility, large in coercivity,light in weight, strong in oxidization resistance and excellent in electromagnetic wave absorption performance.
Owner:SHANDONG UNIV

Magnetic porous cobalt hollow ball electromagnetic wave absorption material, preparation method and application thereof

The invention relates to a magnetic porous cobalt hollow ball electromagnetic wave absorption material, a preparation method and application of the material. The magnetic porous cobalt hollow ball electromagnetic wave absorption material is composed of monodispersed porous hollow balls, wherein the external diameter of each porous hollow ball is 2-6 microns, and the thickness of each ball shell is 100-200nm. The hollow balls are formed by cobalt particles, wherein the diameter of each cobalt particle is 60-200nm, and 10-100nm air voids exist among the cobalt particles. The preparation method includes the steps of using precursors like cobaltous acetate and precipitants like urea, and polyving akohol or polymethyl methacrylate or polyvinylpyrrolidone as surfactants, enabling the surfactants to be dissolved in ethyl alcohol solvents or methanol solvents to obtain cobaltous hydroxides through reaction, and enabling the cobaltous hydroxides and potassium borohydride to be reacted in water or ethanol solutions to obtain the monodispersed porous cobalt hollow balls. The prepared porous cobalt hollow ball material is good in evenness and dispersity, small in density, strong in magnetism and good in electromagnetic wave absorption performance and can be used as the electromagnetic wave absorption material.
Owner:SHANDONG UNIV

Method for preparing natural-cellulose based magnetic porous carbon and application of natural-cellulose based magnetic porous carbon

The invention discloses a method for preparing natural-cellulose based magnetic porous carbon. The method comprises the steps: firstly, soaking natural cellulose into a strongly-alkaline solution, carrying out activation for 0.5 to 24 hours, then, carrying out water washing until the activated cellulose is neutral, carrying out filtering, carrying out drying, then, putting the activated cellulose into a metal salt solution with a catalytic action, carrying out stirring for 0.5 to 24 hours, carrying out filtering, and carrying out drying, so as to obtain a cellulose/metal salt mixture precursor; and calcining the obtained cellulose/metal salt mixture precursor for 0.5 to 12 hours at the temperature of 400 DEG C to 1,000 DEG C in a reducing atmosphere, naturally cooling the calcination product to room temperature, thereby obtaining the natural-cellulose based magnetic porous carbon. According to the method, the raw materials are cheap and readily available, the equipment and procedures are simple and are easy in operation, and the method is pollution-free, is low in cost and facilitates industrialized and large-scale production; and the prepared composite material has properties of both magnetic nano-metal materials and porous carbon materials, so that the requirements of wave absorbing materials on electromagnetic wave dissipation capability and impedance matching are excellently met, and the electromagnetic wave absorption property is excellent.
Owner:HENAN UNIVERSITY

Preparation method of Ni-Co alloy embedded N-doped graphite carbon capsule composite wave-absorbing material

The invention provides a preparation method of an Ni-Co alloy embedded N-doped graphite carbon capsule composite wave-absorbing material, and belongs to the field of synthesis of composite materials. The method is characterized in that Ni(OH)2 particles are designed and synthesized, an Ni(OH)2 methanol solution is prepared, and Ni(OH)2/ZIF-67 is synthesized by adding a certain quantity of the Ni(OH)2 solution during the synthesis of ZIF-67; the Ni(OH)2/ZIF-67 is taken as a template, trishydroxymethylaminomethane is taken as a buffer agent, in situ polymerization of dopamine hydrochloride is carried out on the surface to form Ni(OH)2/ZIF-67@PDA, the ZIF template is subjected to self-etching during dopamine coating, and a hollow dodecahedral capsule is formed; high-temperature calcination and aftertreatment are carried out to prepare the Ni-Co alloy embedded N-doped graphite carbon capsule composite wave-absorbing material (Air@NCs euro Ni-Co). The synthetic method provided by the invention has universality, and N-doped graphite carbon capsule composite wave-absorbing materials embedded with different alloys (Fe-Co, Co-Cu, Co-Zn, FeCoNi, FeCoZn ternary alloy, and the like) can be synthesized. The Ni-Co alloy embedded N-doped graphite carbon capsule composite wave-absorbing material prepared by a three-step method has good wave-absorbing properties.
Owner:DALIAN UNIV OF TECH

Method for preparing C-SiO2-Fe/M magnetic mesoporous composite material for electromagnetic wave adsorption coating

The invention relates to a method for preparing a C-SiO2-Fe / M magnetic mesoporous composite material for an electromagnetic wave adsorption coating and belongs to the method for preparing the electromagnetic wave adsorption coating. In the method, magnetic metals are introduced into an ordered mesoporous carbon-silicon oxide compound by combining a solvent evaporation induced self-assembly method with in-situ carbothermic reduction technology, wherein triblock copolymer F127 serves as a structure directing agent; furfuryl alcohol serves as a carbon source; TEOS serves as a silicon source, ferric chloride and M salt serve as metal sources. Metal ions are reduced into metal particles in the carbonation process and the metal particles are highly dispersed in a carbon matrix, so that the ordered mesoporous structure of the compound does not be damaged. Therefore, in the preparation method, the operation of inducing the magnetic components and forming holes can be simultaneously completed, effective adsorption of the electromagnetic wave is ensured, the adsorption frequency range is convenient to expand, the aim of the 'thin, light, wide and strong' composite material is fulfilled, and the method can be widely applied to civilian and military and is more practical.
Owner:NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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