The invention discloses an organic optoelectronic material with the indeno-phenanthroline structure and a preparing method and application thereof, and belongs to the technical field of organic optoelectronic materials. The organic optoelectronic material has the molecular structure shown in the formula I (please see the specification), wherein R1 and R2 are one of hydrogen, phenyl and dibenzofuran, R3 is one of hydrogen, phenyl, polycyclic conjugation aryl with the 10-60 carbon number and aromatic heterocyclic radical containing N, S and O atoms. As the organic optoelectronic material contains the indeno-phenanthroline structure, the larger rigid flat structure is formed, the high electron mobility and the large electron affinity are provided, and transmission of injected electrons is greatly improved.