The invention discloses a hole transport self-
assembly material with a novel anchoring group, a preparation method of the hole transport self-
assembly material, a
perovskite solar cell and a preparation method of the
perovskite solar cell. According to the hole transport self-
assembly material,
tropolone serves as an anchoring group,
tropolone has a unique seven-membered ring structure and an
enol-
ketone tautomerism characteristic, keto groups and
enol hydroxyl groups in molecules can form a stable bidentate coordination structure with a substrate, and a good anchoring effect is achieved. And
energy level alignment and formation of a facing stacking structure are facilitated, so that charge transfer among molecules is facilitated. Experimental data show that the preparation method of the hole-transport self-assembly material provided by the invention is simple, a
dopant does not need to be added, the cost is low, byproducts in the synthesis process are few, separation and purification are easy, the hole-transport self-assembly material is applied to a
perovskite solar cell, and the hole-transport self-assembly material can be applied to the
perovskite solar cell. The
photoelectric conversion efficiency of 22.35% or above and the high open-circuit
voltage (Voc) of 1.10 can be obtained, charge
coupling is weak, and the method has wide application prospects.