The invention discloses a preparation method of an intelligent glass cathode electrochromic layer coating material. In a process of preparing the intelligent glass cathode electrochromic layer tungsten oxide coating material, various oxides are fully and uniformly mixed by using slip casting, so that the density and uniformity of a target material are improved, and then the service life of the target material is prolonged. The chemical stability of the tungsten oxide material is improved by adding a second oxide into the tungsten oxide. Oxygen vacancies are formed by the vacuum treatment in asintering process, so that the material has conductivity, and stable sputtering is facilitated. In addition, a process of staged heating sintering is adopted, and other gases are added in argon gas, so that the film-forming rate can be improved, the surface roughness can be reduced, the sputtering rate can be improved, the film roughness can be reduced, the activation of equipment can be improved,the production cost can be reduced, the application of the tungsten oxide film in electrochromic devices is greatly improved, the production requirements are met, and the market promotion and productpopularization are facilitated.