The invention relates to a fouling and slagging resistance and high temperature and corrosion resistance ceramic paint and a preparation and usage method thereof. The ceramic paint comprises, by mass, the components of 20-30% of filler, 23-29% of binders, 0.8-1.2% of addition agents and the balance water. According to the ceramic paint, the formula component and ratio are reasonable, the filler granularity is small, granularity matching among different filler components is reasonable, and the matching compatibility of the filler and a binder system is good. A ceramic coating prepared by spray coating can resist high temperature 1320 DEG C, is thinner, has the functions of resisting fouling and slagging and resisting high temperature and corrosion, and cannot be pulverized and fall off in a long-term high-temperature operating environment; the high emissivity above 0.95 can be still kept at high temperature and is close to the thermal expansion coefficients of metal, and heat transfer can be enhanced; the coating integrates chemical inertness and passivation protection into a body, and therefore a high-temperature corrosion environment is prevented from corroding the metal through the compact ceramic coating; meanwhile, due to the fact that the coating has the self-cleaning effect, the coating can be applied easily and conveniently.