This invention provides a fibrous flexible aqueous
zinc battery, its preparation method, and its applications. The invention utilizes an electro-induced
interfacial polymerization method to construct a tightly adhered in-situ composite hydrogel
electrolyte on the
electrode surface. Compared to traditional gel electrolytes, due to the enrichment of charged components under an
electric field before in-situ
polymerization, a stronger interfacial interaction is formed between the
electrode and the composite hydrogel
electrolyte, thus achieving a highly stable
electrode-gel
electrolyte interface. The in-situ composite hydrogel electrolyte is rich in functional groups such as
amide bonds and carboxyl groups. These groups can effectively induce uniform deposition of
zinc ions and inhibit the activity of
free water molecules at the interface, thereby effectively suppressing
dendrite growth and undesirable side reactions, and effectively improving the cycle stability of the aqueous
zinc battery under high zinc utilization. The flexible aqueous zinc battery of this invention can be applied to wearable electronic devices, providing a safe, high-performance, and highly stable power supply solution for next-generation flexible wearable devices.