281results about "Molecular-sieve silicates" patented technology

A process for easily synthesizing a zeolite substance containing an element having a large ionic radius in the framework at a high ratio. This process comprises the following first to fourth steps: First Step: a step of heating a mixture containing a template compound, a compound containing a Group 13 element of the periodic table, a silicon-containing compound and water to obtain a precursor (A); Second Step: a step of acid-treating the precursor (A) obtained in the first step; Third Step: a step of heating the acid-treated precursor (A) obtained in the second step together with a mixture containing a template compound and water to obtain a precursor (B); and Fourth Step: a step of calcining the precursor (B) obtained in the third step to obtain a zeolite substance.

The invention concerns a heat-stable ordered mesoporous or mesostructured material comprising a mineral phase wherein are dispersed particles of nanometric dimension at least partly crystaline, the global crystallinity index of said mesostructured or ordered mesoporous material being less than 10% in volume. The invention also concern a method for obtaining such a material.

The invention provides methods for rapidly synthesizing heteroatom containing zeolites including Sn-Beta, Si-Beta, Ti-Beta, Zr-Beta and Fe-Beta. The methods for synthesizing heteroatom zeolites include using well-crystalline zeolite crystals as seeds and using a fluoride-free, caustic medium in a seeded dry-gel conversion method. The Beta zeolite catalysts made by the methods of the invention catalyze both isomerization and dehydration reactions.

The invention concerns a method for preparing a crystalline metalloaluminosilicate by direct synthesis using at least one source of aluminium and, as the source of silicon and as the source of at least one other metal M, at least one lamellar siliceous material containing metals in its framework. The invention also concerns the novel solids obtained, in particular solids with a given zeolitic structure containing particular metals in its zeolitic framework.

A method is disclosed for preparing crystalline titanosilicate zeolite TS-1 from a reaction mixture containing only sufficient water to produce zeolite TS-1. In one embodiment, the reaction mixture is self-supporting and may be shaped if desired. In the method, the reaction mixture is heated at crystallization conditions and in the absence of an added external liquid phase, so that excess liquid need not be removed from the crystallized product.

The present invention relates to a method of preparing a microporous crystalline molecular sieve Inorganic gel having mesoporous skeleton, comprising following steps: (a) adding a meso-SDA (meso-Structure Directing Agent) into a gel composition of synthesizing molecular sieve, (b) subjecting the mixture obtained in the above step (a) to crystallization by a hydrothermal reaction, a microwave reaction, a dry-gel synthesis, etc., and (c) removing selectively organic materials from the resulted material obtained in the above step (b) by a calcination or a chemical treatment. Molecular sieve having mesoporous skeleton synthesized by the present invention exhibits, as compared with conventional zeolite, a good molecule diffusion ability and a greatly improved catalytic activity.

Titanium-MWW zeolite is prepared by heating a gel formed from a titanium compound, a silicon source, a boron source, an MWW-templating agent, and water at a temperature in the range of 35° C. to 75° C. for a period of 8 to 30 hours to form a pre-crystallized gel, and heating the pre-crystallized gel to a temperature in the range of 160° C. to 190° C. for a period of 5 or more days to form the titanium-MWW zeolite. The zeolite, after it is contacted with an acid, is useful in olefin epoxidation with hydrogen peroxide.

A mesoporous silica has uniform mesopores and a periodic structure, which contains a Zr element in the form of a Si-O-Zr bond and wherein the Zr content in the Si-O-Zr bond, represented by [Zr/(Si+Zr)] is 0.05 to 20 mole %. The mesoporous silica is superior in alkali resistance and is suitably used particularly as a separation membrane (e.g. a ceramic membrane) and a catalytic support for solid-liquid system, in which an alkaline liquid may be used.

Mesoporous ZSM compositions and methods of preparing same are provided. The starting material is an amorphous metallosilicate which is processed into ZSM-type nanocrystals. Upon calcinations, meso-ZSM-nanaocrystals are prepared.

The invention relates to a hierarchical porous titanium-silicon molecular sieve as well as a preparation method thereof and an olefin epoxidation method. The hierarchical porous titanium-silicon molecular sieve has a grain size of 600-700 nm, has relative crystallinity of 55-64%, has a specific surface area of 660-725 m<2>/g, has a total pore volume of 0.55-0.7 cm<3>/g, and has a mesoporous volumeof 0.3-0.5 cm<3>/g; the volumes of pores with the pore diameters of 0.5-2 nm of the hierarchical porous titanium-silicon molecular sieve account for 15-36% of the total pore volume, the volumes of pores with the pore diameters of 2-4 nm account for 1-25% of the total pore volume, and the volumes of the pores with the pore diameters of 4-16 nm account for 20-45% of the total pore volume, and the volumes of the pores with the pore diameters greater than 16 nm account for 20% or lower of the total pore volume. The hierarchical porous titanium-silicon molecular sieve disclosed by the invention isgreater in mesoporous volume, is higher in proportion of the total pore volume, and can remarkably increase an olefin conversion rate and can improve selectivity of alkyleneoxide while used for olefin oxidization reaction.

Titanium-containing molecular sieves are prepared by adding an aqueous template solution to a mixture of tetraalkyl orthosilicate and tetraalkyl orthotitanate, crystallizing the reaction mixture in an autoclave and separating the solid obtained optionally, the solid is washed and calcined. The titanium-containing molecular sieves can be used as catalysts, inter alia in the epoxidation of olefins.

The invention relates to a titanium silicon molecular sieve, and a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing a titanium source, a template tetraalkoxysilane and water, carrying out hydrolysis and remove alcohol; and (2) adding a compound with a structure as shown in a formula (I) and carrying out crystallization. The method can prepare the titanium silicon molecular sieve containing more mesopores; and the prepared titanium silicon molecular sieve is applicable to catalysis of the reactions of macromolecules.

The present invention relates to microporous molecular sieve materials and their analogue molecular sieve materials having a crystalline unilamellar or multilamellar framework with a single unit cell thickness in which layers are aligned regularly or randomly, the molecular sieve materials being synthesized by adding an organic surfactant to the synthesis composition of zeolite. In addition, the present invention relates to micro-mesoporous molecular sieve materials activated or functionalized by dealumination, ion exchange or other post treatments, and the use thereof as catalyst. These novel materials have dramatically increased external surface area by virtue of their framework with nano-scale thickness, and thus exhibit improved molecular diffusion, and thus have much higher activities as catalyst and ion exchange resin than conventional zeolites. In particular, the materials of the present invention exhibit high reactivity and dramatically increased catalyst life in various organic reactions such as carbon-carbon coupling, alkylation, acylation, etc. of organic molecules.

A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO₄-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.

A process for preparing a zeolitic material, comprising (i) preparing a mixture comprising the at least one silicon containing precursor compound from which the zeolitic framework is formed, at least one pore forming agent, and at least one polymer which has an essentially spheroidal geometry in the mixture; (ii) crystallizing the zeolitic material from the mixture obtained in (i) to obtain the crystallized zeolitic material in its mother liquor.

A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of refractory oxide containing at least 97% by volume of pores having a pore size ranging from about 15 Å to about 30 Å and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2 theta (θ). The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.

The invention relates to the field of catalytic materials and in particular provides a titanium silicalite molecular sieve, a synthetic method and application of the titanium silicalite molecular sieve. The titanium silicalite molecular sieve is composed of the following elements in percentage by mass: 0.01-5% of precious metals, silicon, 0.02-8% of titanium and oxygen, wherein the I960/I550 valueis 0.6-0.9; the U480/U330 value is 0.5-5; and the N-116/N-112 value is 0.01-0.2. The invention further provides a cyclic ketone oxidation method. The cyclic ketone oxidation method comprises the following step: contacting cyclic ketone, an oxidizing agent and a catalyst, wherein the catalyst contains the titanium silicalite molecular sieve disclosed by the invention. Compared with the prior art,the titanium silicalite molecular sieve disclosed by the invention has the advantages that diffusion of the reactants and product is facilitated in an oxidation reaction, so that oxidative activity isfully achieved, and the selectivity is improved. For example, when applied to a reaction in which ring molecules, particularly cyclic ketone molecules, participate or are produced, the titanium silicalite molecular sieve can achieve excellent catalytic effects. Moreover, filtration and separation of the catalyst after the reaction can be further facilitated, and industrialized application is easily realized.