The invention discloses a piston type oil-less air compressor. The piston type oil-less air compressor comprises a machine base, a crank case fixed on the machine base, a primary cylinder I, a primary cylinder II, a primary cylinder III, an intermediate cooler, a primary air-water separator, a secondary cylinder I, a secondary cylinder II, an after-cooler, a secondary air-water separator and an air storage tank fixed on the machine base. The primary cylinder I, the primary cylinder II and the primary cylinder III are fixed on the crank case respectively and distributed in a fan-shaped mode, an included angle between the primary cylinder I and the primary cylinder II and between the primary cylinder III and the primary cylinder II are 40-55 degrees, and the secondary cylinder I and the secondary cylinder II are arranged on the left side and the right side of the crank case respectively. By adopting the technical scheme, the piston type oil-less air compressor is compact in structure, a space occupied by the air compressor is saved, the installing area of a valve is increased, cooling is facilitated, the effective volume flow and exhaust pressure of the piston type oil-less air compressor are improved, an application range is expanded, the service life and the air quality are prolonged and improved, and the working reliability is improved.