The invention discloses a production technology of high-modulus alkali-free glass fiber. The technology comprises steps of preparing raw materials, fusing, wire drawing, winding, glue dipping, drying and detecting. The high-modulus alkali-free glass fiber comprises following chemical components by weight: 57-60% of SiO2, 0.5-1.5% of TiO2, 12-14% of Al2O3, 0.2-0.5% of Fe2O3, 22-23% of CaO, 0.1-0.5% of LiO2, 2.5-3% of MgO, 0.3-0.5% of Na2O, 0.1-0.5% of K2O and 0.2-0.5% of CeO2, wherein the sum of the weight percentages of the components is 100%. The glue dipping step adopts a dipping glue comprising following components by weight: 10 parts of 618 epoxy resin, 1 part of a triethylene tetramine curing agent and 2-4 parts of an acetone diluent. The high-modulus alkali-free glass fiber prepared by the technology is high in elastic modulus, high in product strength, and good in acid resistance and insulating property.