The invention discloses a gas impurity removal and hydrolysis composite tank and a blast furnace gas fine desulfurization system. The gas impurity removal and hydrolysis composite tank comprises a reaction tank body, the reaction tank body is provided with a gas inlet and a gas outlet along the radial direction, three net partition plates are arranged in the reaction tank body, the net partition plates are parallel to the center line of the reaction tank, gas flows along the radial direction of the tank body, the interior of the reaction tank body is divided into a gas distribution chamber, an impurity removal chamber, a catalytic hydrolysis chamber and a gas collection chamber by the net partition plates, a gas inlet is formed in the gas distribution chamber side of the reaction tank body, a gas outlet is formed in the gas collection chamber side of the reaction tank body, an impurity removal agent is placed in the impurity removal chamber, an organic catalytic conversion agent is placed in the catalytic hydrolysis chamber, and gas enters the gas distribution chamber from the gas inlet, uniformly flows to the impurity removal chamber and the catalytic hydrolysis chamber, is converged in the gas collection chamber and then is discharged through the outlet, so that the on-way resistance of the gas is small, the pressure loss is small, and harmful impurities in the blast furnace flue gas can be removed, and organic sulfides can be catalytically hydrolyzed.