The application provides a non-
fluoropolymer, a non-
fluoropolymer composite diaphragm and application, the non-
fluoropolymer includes
polymer A and the
polymer B at least partially coated on the surface of
polymer A, the crosslinking degree of polymer A is X1, the crosslinking degree of polymer B is X2, 5%≤X1≤10%, 50%≤X2≤60%;The non-fluoropolymer composite diaphragm includes base film and
coating layer coated on at least one side of base film.The non-fluoropolymer particles of the application have a higher swelling rate at high temperature, also have the reversible characteristics of absorbing and releasing
electrolyte, the non-fluoropolymer and the non-fluoropolymer composite diaphragm are applied in the battery, when the battery abnormally heats, the non-fluoropolymer swells rapidly, blocks the
ion shuttle channel, avoids the further deterioration of temperature, improves the safety performance of the battery, and when the temperature returns to normal, the non-fluoropolymer particles can restore to the original morphology, restore the
ion shuttle channel, so as to not affect the subsequent cycle performance of the battery.