The invention discloses a method and a device for measuring the content of diffusible hydrogen in the deposited metal of welding materials. Four samples are prepared according to GB / T 3965, and AgBr and NaNO are placed in a dark room. 2 The diffusive hydrogen collector of the solution was opened with magnetic stirring and the test temperature was set, and collected for 72h to make the hydrogen react with AgBr to form Ag. Add Na 2 S 2 O 3 The solution removes excess AgBr, and after cleaning the sample, pour the Ag-containing solution into the filter device to obtain m Ag ,use m Ag and the chemical formula to deduce the hydrogen content of the sample V D ,4 V D The mean is the diffusible hydrogen content H D . The diffusible hydrogen collector is placed in the ultrasonic cleaning device, and there is a heating wire between the adjacent cleaning devices; a magnetic stirring device is installed under the diffusing hydrogen collector, and the water bath heating temperature control device controls the heating wire through thermocouple temperature measurement. The beneficial effect is that the invention can replace the toxic mercury method to ensure the health of workers, break the foreign monopoly on high-end TCD hydrogen detectors, and reduce the cost of enterprises.