The application discloses a kind of
carbon black supported iron
manganese composite oxide cluster catalyst's
Joule heat preparation method and its application in electrocatalytic
nitrate reduction preparation
ammonia, belong to electrocatalytic
ammonia preparation technical field.The catalyst Ketjenblack EC-600JD
carbon black is used as carbon carrier, iron
manganese composite oxide cluster is uniformly dispersed on the surface of carbon carrier, and the carbon carrier is worm-like mesoporous structure, with high specific surface area and high defect concentration.The application uses
sodium citrate as complexing agent,
acetylacetone iron and
manganese acetate as
metal precursor, after complexing, loading, gelation,
freeze drying, the target catalyst is prepared by
Joule heat instantaneous heat treatment under
nitrogen atmosphere;The preparation process has
high heat conversion efficiency, low
energy consumption, can realize atomic dispersion of iron manganese
composite oxide cluster, effectively improves the
exposure degree of catalytic
active site.The catalyst shows high catalytic activity,
high selectivity and excellent stability in electrocatalytic
nitrate reduction preparation
ammonia reaction, and the ammonia preparation
faraday efficiency can reach more than 85%, and the preparation process does not need
noble metal and toxic
reagent, and the process is green and efficient, easy to scale production, can efficiently convert
nitrate wastewater into ammonia, with environmental governance and
nitrogen resource recycling value.