The invention provides an exhaust air catalytic oxidation device utilizing supercritical CO2 solar heat collecting and storing for heating, and belongs to the technical field of solar light heat utilization and exhaust air gas heat utilization. According to the technical scheme, a supercritical CO2 solar heat collecting subsystem, a fuse salt heat storage / heat exchange subsystem, a gas source concentration monitoring filter subsystem, a catalytic oxidation subsystem, a high-temperature smoke power generation subsystem, a heat supply tail end subsystem, a condensate water recycling subsystem, asmoke discharging subsystem and a running monitoring subsystem are included. A tower type solar heat collector is utilized for collecting solar focus heat, the good heat transfer character and transmission performance of supercritical CO2 are utilized, the exhaust air is heated in combination with the fuse salt heat storage technology, gas energy waste can be reduced, the utilization rate in theexhaust air gas catalytic oxidation process is increased, and the high-temperature smoke heat-into-power conversion efficiency is improved.