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95 results about "Double oxide" patented technology

Double-oxide co-coated high-nickel lithium battery positive electrode material and preparation method thereof

InactiveCN108390039ASuppresses the problem of high alkali contentImprove cycle performanceCell electrodesSecondary cellsDecompositionLithium hydroxide
The invention provides a double-oxide co-coated high-nickel lithium battery positive electrode material and a preparation method thereof. A high-nickel ternary precursor material is prepared through aco-precipitation method; and then, vacuum pre-sintering is carried out after fully mixing and ball-milling with lithium hydroxide and calcium hydroxide; later, sulfate, metal oxide titanium oxide, cerium oxide and the like are added into gel synthesized in an organic solvent; and the high-nickel lithium battery positive electrode material coated by a double-oxide layer is obtained after sintering. According to the method in the invention, the problem that the alkali content of the traditional high-nickel ternary material is excessively high in the precursor preparation process is solved; theprepared double-oxide-layer coated high-nickel lithium battery positive electrode material forms a physical isolation layer, so that the corrosion of HF in the electrolyte and the generation of side reactions are inhibited, the high-nickel lithium battery positive electrode material is protected; therefore, the cycling performance of the battery is improved; meanwhile, the introduced sulfate ionsform a stable electrolyte layer, so that the decomposition of the electrolyte is inhibited, and the cycling performance of the battery is further improved.
Owner:CHENDU NEW KELI CHEM SCI CO LTD

A ternary cathode material coated with double oxides and a preparation method thereof

The invention discloses a ternary cathode material coated with double oxides and a preparation method thereof, belonging to the technical field of lithium ion batteries. The preparation method comprises the following steps: (1) adding a ternary cathode material into an organic solvent, and performing ultrasonic dispersing to obtain a first dispersion liquid; (2) adding a titanium source and a silicon source into the same organic solvent as the Step (1), and performing ultrasonically dispersing to obtain a second dispersion liquid; 3) uniformly mixing the first dispersion liquid and the seconddispersion liquid, dropwise adding water according to a stoichiometric ratio, stirring and reacting, and evaporating all the solvents to dryness to obtain a composite material precursor; (4) calcinating the composite material precursor to obtain the ternary cathode material coated with double oxides. The different film-forming rates of silicon oxide and titanium oxide during calcination at high temperature ensure the uniform distribution of the final coating layer of the whole. The two oxides jointly form the coating together, which has the effect of 1+1 > 2 on the coating of the cathode material, not only is the cycling stability of the material improved, but also the rate performance of the material is improved.
Owner:TIANNENG SAFT ENERGY JOINT CO
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