63 results about "Flusulfamide" patented technology

A bio-electrode composition includes (A) an ionic material and (B) a silicon material powder. The component (A) is a polymer compound containing a repeating unit-a having a structure selected from an ammonium salt, a sodium salt, a potassium salt, and a silver salt of any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide. Thus, the present invention provides a bio-electrode composition capable of forming a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, is light-weight, can be manufactured at low cost, and can control significant reduction in the electric conductivity even when the bio-electrode is wetted with water or dried; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.

The invention provides a detection method of residual quantity of indazole flusulfamide and metabolite IT-4 thereof. The method comprises the following steps: (1) preparing standard solutions, namely weighing a standard substance, dissolving and making up to volume through an organic solvent to prepare a standard stock solution, and gradually diluting the standard stock solution to prepare the standard working solutions with serial concentration; (2) extracting a residue from a sample; (3) purifying, namely weighing an extracting solution in the step (2), placing the weighed solution in a centrifuge tube, and then adding an adsorbent, and centrifuging to obtain supernatant; (4) detecting by ultra high performance liquid chromatography-tandem mass spectrometry (UHPLC-MSMS); (5) establishing a standard curve; and (6) analyzing a result. The detection method provided by the invention is capable of fast, flexibly and accurately determining the residual quantity of indazole flusulfamide and metabolite IT-4 thereof, and a new detection technology is provided for detecting the novel bactericide, indazole flusulfamide, and metabolite thereof.

The invention discloses a cyclohexyl flusulfamide-containing bactericidal composition. The bactericidal composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from cyclohexyl flusulfamide; the active ingredient B is selected from one of the following compounds: cyazofamid, dimethomorph, metalaxyl or salts thereof, propamocarb, cymoxanil and iprovalicarb; a mass ratio of the active ingredient A to the active ingredient B is 1:70-70:1. The composition has high activity on multiple diseases on various crops and has an obvious synergistic effect, and a bactericidal spectrum is widened. Moreover, the bactericidal composition has the characteristics of small dosage, rain wash resistance and obvious synergistic effect.

The invention provides a synthetic method of hexamethylene flusulfamide. The synthetic method comprises the following steps: reacting to obtain 2-oxocyclohexyl ammonium sulphonate and ammonium sulfate by adopting cyclohexanone, 1, 4-dioxane, sulfur trioxide and ammonia as the raw materials; washing via reaction product through absolute methanol, and leaching to separate ammonium sulfate; and then carrying out reaction among 2-oxocyclohexyl ammonium sulphonate, oxalyl chloride and 2-trifluoromethyl-4-chloroaniline to obtain hexamethylene flusulfamide. According to the synthetic method provided by the invention, KOH solution is replaced via the ammonia, thus, the reaction endpoint is easily controlled; the byproduct ammonium sulfate can be used as chemical fertilizer after being separated, and the generation of three wastes such as waste barium sulfate can be removed; the reaction is easy to operate, the post-processing is simple to carry out, the product is high in purity and high in yield, and the method is suitable for large-scale industrial application.

The invention discloses a fungicidal composition. The fungicidal composition contains an active ingredient A and an active ingredient B, wherein the active ingredient A is cyclohexyl flusulfamide, the active ingredient B is any compound selected from cyprodinil, pyrimethanil, diethofencarb, iprodione, procymidone and dimethachlon, and the weight ratio of the active ingredient A to the active ingredient B is (1: 70) to (70: 1). The composition disclosed by the invention has relatively high activity to various diseases of a variety of crops and has obvious synergism, and the fungicidal spectrum is enlarged; the composition has the characteristics of small dosage, rainwater washing resistance and obvious synergism.

The present invention relates to a pesticide composition and a fungicide, wherein the pesticide composition contains Dufulin and an amide fungicide, a weight ratio of the Dufulin to the amide fungicide is (50-1):(1-50), and the amide fungicide is any one selected from metalaxyl-M, metalaxyl, fluxapyroxad, fluopyram, boscalid, thifluzamide, flutolanil, mandipropamid, flusulfamide, silthiopham, fluopicolide, zoxamide, ofurace, fenoxanil, fenhexamid and ethaboxam. The present invention further provides a fungicide, wherein the pesticide composition accounts for 0.1-90% of the total weight of the fungicide. According to the present invention, the pesticide composition and the fungicide are used for prevention and control of viral and fungal diseases of a variety of crops, have significant synergy effects, and can achieve effects of control effect improving, drug resistance delaying, antibacterial spectrum expanding, drug consumption reducing, cost reducing, working time saving, labor saving, and the like.

The invention discloses preparation and application of a shed frame pear tree shaping wound healing agent. An antibacterial agent, an adhesive, a film-forming agent, chitin, bromelain and water are taken as raw materials to prepare a gel type wound healing agent under acidic conditions, wherein the antibacterial agent is formed by compounding flutriafol, flusulfamide and polyoxins. By mass, the usage amount of the chitin accounts for 2-4% of the total amount, and the usage amount of bromelain accounts for 1.5%-3.5% of the total amount by mass. Healing promoting performances of the wound healing agent are improved by adding of the chitin and the bromelain. On the one hand, waterproof and oil-repellent functions are strong; on the other hand, the healing rate of pear tree wounds with intact or incomplete edges has been greatly increased and reaches 85% or above, and the shed frame pear tree shaping wound healing agent is non-toxic, harmless, environmentally friendly and low-carbon.

The invention relates to a bactericidal composition containing mandipropamid. A preparation of the bactericidal composition contains mandipropamid, indazole flusulfamide and fluopyram, wherein the ratio of the three effective components in the preparation in parts by weight is 1 to (0.01-60) to (0.01-60); the parts of the effective components in the bactericidal composition preparation account for 1%-60% of total parts by weight of the overall preparation; and the bactericidal composition can be prepared into pesticide preparation dosage forms, namely wettable powder, a suspending agent, missible oil, a microemulsion, an emulsion in water, a granule and a water dispersible granule. The bactericidal composition provided by the invention has high affinity on a wax coat on the plant surface; when the bactericidal composition is sprayed on the plant surface, and is participated and dried, most of active ingredients are adsorbed by the wax coat, and are difficult to rinse out by rainwater; one part of active components penetrates into the plant tissue; the high-activity component absorbed into the plant tissue is used for inhibiting growth of mycelium; the overall blade is prevented from being infected by the bacteria; and the stability, high efficiency and long lasting period of medicines are ensured.

A bio-electrode composition contains (A) a composite of an ionic polymer material and particles. The component (A) contains the particles bonding to the polymer containing a repeating unit having a structure selected from the group consisting of salts of ammonium, lithium, sodium, potassium, and silver formed with any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide. Thus, the present invention provides: a bio-electrode composition capable of forming a living body contact layer for a bio-electrode which is excellent in electric conductivity and biocompatibility, light-weight, and manufacturable at low cost, and which prevents significant reduction in the electric conductivity even when wetted with water or dried; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.

The present invention provides a bio-electrode composition including (A) an ionic material and (C) a metal powder, wherein the component (A) is a polymer compound containing a repeating unit-a having a structure selected from the group consisting of an ammonium salt, a sodium salt, a potassium salt, and a silver salt of any of fluorosulfonic acid, fluorosulfonimide, and fluorosulfonamide. This can form a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried.

A bio-electrode composition includes (A) an ionic material and (B) a lithium titanate powder. The component (A) is a polymer compound containing a repeating unit-a having a structure selected from an ammonium salt, a sodium salt, a potassium salt, and a silver salt of any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide. Thus, the present invention provides a bio-electrode composition capable of forming a living body contact layer for a bio-electrode that is excellent in electric conductivity and biocompatibility, is light-weight, can be manufactured at low cost, and can control significant reduction in the electric conductivity even when the bio-electrode is wetted with water or dried; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.

Providing a novel control agent for soft rot and a novel control method for the same. A compound having no antibacterial activity against Erwinia carotovora but having a control activity against fungi on soil surface, specifically containing, as the active ingredient, a fungicide comprising any of a strobilurin compound such as azoxystrobin and kresoxim-methyl, an azole compound such as triflumizol, cyazofamid, amisulbrom, and thiophanate-methyl, a carboxamide compound such as penthiopyrad and boscalid, a sulfonamide compound such as flusulfamide, an organic chlorine compound such as chlorothalonil, a dicarboximide compound such as pro-cymidone and iprodione, a phenylpyrrole compound such as fludioxonil, an anilinopyrimidine compound such as mepanipyrim, and a guanidine compound such as iminoctadine is the control agent for plant soft rot, which is applied to plant cultivation soil.

The invention discloses an efficient pesticide composition containing cyclohexyl flusulfamide. The pesticide composition comprises an active component A and an active component B, wherein the active component A is selected from cyclohexyl flusulfamide; the active component B is any one selected from thioneb, mancozeb, propineb and zineb; and a weight ratio of the active component A to the active component B is 1 : 80-60 : 1. The composition has synergistic effects for a plurality of diseases harmful to agricultural production, reduces pesticide dosage, reduces residual amount of the pesticide on the crops, alleviates environmental pollutions, is safe to human and animals, and has good environment compatibility. The diseases can not easily produce resistance to the composition.

The invention discloses a bactericidal composition containing cyclohexyl flusulfamide and fluxapyroxad and an application of the bactericidal composition. The bactericidal composition takes cyclohexyl flusulfamide and fluxapyroxad as major active ingredients at a mass ratio ranging from 1:50 to 70:1. The bactericidal composition is applicable to prevention and control of diseases of cereals, fruit trees and vegetables, has a higher synergetic effect, overcomes and retards drug resistance of pathogens, is high in bactericidal speed and long in lasting period, lowers application cost, and has an obviously better prevention and control effect than a single agent. The composition can be used for the prevention and the control of fungoid diseases of crops, particularly the fungoid diseases such as venturia inaequalis, sclerotiniose, botrytis, powdery mildew and brown blotch, and has a better effect than that of a single agent.

The invention discloses an efficient sterilization composition containing hexamethylene flusulfamide. The sterilization composition comprises an active component A and an active component B. The active component A is selected from the hexamethylene flusulfamide. The active component B is one compound selected from flusilazole, epoxiconazole, myclobutanil, tetraconazole, flutriafol and tricyclazole. The weight ratio of the active component A to the active component B is 1:30-80:1. The sterilization composition has high activity for a plurality of diseases of a plurality of crops and significant synergistic effects, and expands the bacteriocidal spectrum. The sterilization composition has characteristics of little dosage, capability of bearing rain wash and the significant synergistic effects.

Current methods for making polyfluorosulfonamido amines, which involve the use of a diamine reactant, provide low yields and produce an undesirable fluorine containing bis-sulfonamide by-product representing an economic loss. The bis-sulfonamide by-product is particularly undesirable because it shares very similar physical properties with the desired monoamine product thus making isolation of the desired polyfluorosulfonamido amine product difficult and costly. Furthermore, instead of the efficient incorporation of fluorine to make the desired polyfluorosulfonamido amine product, the bis-sulfonamide by-product constitutes a substantial loss of costly fluorinated starting material. The bis-sulfonamide by-product also constitutes an undesirable impurity that can worsen surfactancy, repellency, or other performance characteristics of the desired polyfluorosulfonamido amine product. The present invention provides a method of making a polyfluorosulfonamido amine without the production of a bis-sulfonamide by-product by reacting a polyfluoroalkylsulfonic compound with a monoamino amide rather than with a diamine reactant as in previously known methods.

The present invention discloses a sterilizing composition containing benzovindiflupyr. The sterilizing composition is a sterilizing composition containing an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from benzovindiflupyr while the active ingredient B is selected from any one of the following compounds: captan and cyclohexyl flusulfamide, and the weight ratio of the active ingredient A and the active ingredient B is 1:80 to 60:1. The composition disclosed by the present invention has high activity to various diseases on various crops and has a remarkable synergism effect, so that the sterilizing spectra are expanded. The composition has the characteristics of small dosage, resistance to rainwash and remarkable synergism.

The invention discloses a sterilization composition containing cyclohexyl flusulfamide. The sterilization composition comprises an active ingredient A and an active ingredient B; the active ingredient A is cyclohexyl flusulfamide; the active ingredient B is one compound randomly selected form triflumizole, polyoxins, prochloraz or a salt thereof, carbendazim, and thiophanate methyl; and the weight ratio of the active ingredient A to the active ingredient B is 1:60-80:1. The sterilization composition possesses relatively high activity on a plurality of diseases of a plurality of crops, and obvious synergistic effect; and sterilization spectrum is widened. In addition, the sterilization composition possesses characteristics such as small dose, rainwater wash resistance, and obvious synergy.

An additive polymer comprising recurring units derived from a fluorosulfonamide-substituted styrene and recurring units derived from a stilbene, styrylnaphthalene, dinaphthylethylene, acenaphthylene, indene, benzofuran, or benzothiophene derivative is added to a polymer capable of increasing alkali solubility under the action of acid to formulate a resist composition. The resist composition can minimize outgassing from a resist film during the EUV lithography and form a resist film having a hydrophilic surface sufficient to prevent formation of blob defects on the film after development.

The invention provides a composite pesticide of cyclohexyl flusulfamide and chlorothalonil. The mole ratio of cyclohexyl flusulfamide to chlorothalonil is (1: 2)-(2: 1) and a coordination bond is arranged between the two molecular structures to strengthen the pesticide effect. When the composite pesticide is in emulsion type, the content of a solvent is 50-65wt% and an emulsifier is one or several of a pesticide emulsifier 0203, a pesticide emulsifier 0201, GFC, OP-10, tween-60 and a pesticide emulsifier OX-2568, which are capable of well emulsifying cyclohexyl flusulfamide and chlorothalonil in a water solution; when the composite pesticide is in wettable powder type, the dosage of a disperser is 5-15wt% and the disperser is one or several of sodium lignin sulfonate, sodium 1-naphthalenesulfonate, polyethylene glycol and alkylphenol polyoxyethylene phosphate, which are capable of forming a favorable dispersing system with the water solution of cyclohexyl flusulfamide and chlorothalonil. The composite pesticide has the purpose of favorably preventing and treating the downy mildew and the gray mold of the plants. According to the composite pesticide, the concentration of active ingredients is relatively low, the dosage is relatively less, the spraying is carried out once to twice and 25-50% of synergistic function is brought to the prevention and treatment of the downy mildew and the gray mold.

The present invention provides a bio-electrode composition comprising a polymer compound having a repeating unit A that contains silver salt of fluorosulfonic acid, silver salt of fluorosulfonimide, or silver salt of fluorosulfonamide. This can form a living body contact layer for a bio-electrode with excellent electric conductivity, biocompatibility and light weight, which can be manufactured at low cost and does not cause large lowering of the electric conductivity even when it is wetted with water or dried. The present invention also provides a bio-electrode in which the living body contact layer is formed from the bio-electrode composition and a method for manufacturing the bio-electrode.

The invention provides a detection method of residual quantity of indazole flusulfamide and metabolite IT-4 thereof. The method comprises the following steps: (1) preparing standard solutions, namely weighing a standard substance, dissolving and making up to volume through an organic solvent to prepare a standard stock solution, and gradually diluting the standard stock solution to prepare the standard working solutions with serial concentration; (2) extracting a residue from a sample; (3) purifying, namely weighing an extracting solution in the step (2), placing the weighed solution in a centrifuge tube, and then adding an adsorbent, and centrifuging to obtain supernatant; (4) detecting by ultra high performance liquid chromatography-tandem mass spectrometry (UHPLC-MSMS); (5) establishing a standard curve; and (6) analyzing a result. The detection method provided by the invention is capable of fast, flexibly and accurately determining the residual quantity of indazole flusulfamide and metabolite IT-4 thereof, and a new detection technology is provided for detecting the novel bactericide, indazole flusulfamide, and metabolite thereof.

The invention discloses a high-efficient bactericidal composition containing hexamethylene flusulfamide. The composition comprises an active component A and an active component B, wherein the active component A is selected from hexamethylene flusulfamide, the active component B is any one compound selected from the following compounds: triazolone, pyrimidine nucleotide antibiotic, JS399-19, and bromothalonil, and the weight ratio of the active component A to the active component B is 1:60 to 80:1. The composition has a high activity on a plurality of pest diseases on a plurality of crops, has a prominent synergetic effect, enlarges the bactericidal spectrum, and has the characteristics of little drug using amount, rain washing resistance, and prominent synergetic effect.

The invention discloses a sterilization composition containing indazole flusulfamide and zinc thiazole; the sterilization composition comprises indazole flusulfamide as a first effective component, zinc thiazole as a second effective component and common auxiliary components; and the weight ratio of indazole flusulfamide to zinc thiazole is (10:1) to (1:20). Lots of experiments show that the sterilization composition disclosed by the invention has obvious synergistic effects and excellent control effects to a variety of fungal diseases and bacterial diseases on crops.

A bio-electrode, excellent in electric conductivity and biocompatibility, light-weight, manufacturable at low cost, and free from large lowering of the electric conductivity even though it is wetted with water or dried, includes an electro-conductive base material and a living body contact layer formed on the electro-conductive base material. The living body contact layer is a cured material of a bio-electrode composition including (A) an ionic material and (C) a metal powder, wherein the component (A) is a polymer compound containing a repeating unit-a having a structure selected from an ammonium salt, a sodium salt, a potassium salt, and a silver salt of any of fluorosulfonic acid, fluorosulfonimide, and fluorosulfonamide.

The invention relates to an insecticidal ointment containing cyclohexyl flusulfamide and prothioconazole, and belongs to the field of pesticides and preparations thereof. The insecticidal ointment isprepared by mixing cyclohexyl flusulfamide, prothioconazole and an auxiliary agent, the cyclohexyl flusulfamide accounts for 0.1-40% of the total weight of the insecticidal ointment, the prothioconazole accounts for 0.1-50% of the total weight of the insecticidal ointment, and the balance is the auxiliary agent. The insecticidal ointment is prepared from cyclohexyl flusulfamide and prothioconazolein a weight ratio of 5:1, 2:1, 1:1, 1:2 or 1:5. The ointment disclosed by the invention is long in lasting period, small in environmental pollution and simple and convenient to apply.

The invention discloses a cyclohexyl flusulfamide-containing bactericidal composition. The bactericidal composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from cyclohexyl flusulfamide; the active ingredient B is selected from one of the following compounds: cyazofamid, dimethomorph, metalaxyl or salts thereof, propamocarb, cymoxanil and iprovalicarb; a mass ratio of the active ingredient A to the active ingredient B is 1:70-70:1. The composition has high activity on multiple diseases on various crops and has an obvious synergistic effect, and a bactericidal spectrum is widened. Moreover, the bactericidal composition has the characteristics of small dosage, rain wash resistance and obvious synergistic effect.