The invention discloses 2-nitro-2-aza adamantane-4, 6, 8-triol trinitrate and a preparation method of the 2-nitro-2-aza adamantane-4, 6, 8-triol trinitrate. According to the method, 9-hydroxyl bicyclo [3.3. 1] nonane-2, 6-diketone is used as a raw material, the 2-nitro-2-azaadamantane-4, 6, 8-triol trinitrate is finally synthesized through the steps of hydrazone formation, elimination, epoxidation, cyclization, acetylation, nitration and the like, the compound has higher density and energy, the synthesis method is simple, the yield is high, and the performance is stable.