Metal oxide structures, devices, and fabrication methods are provided. In addition, applications of such structures, devices, and methods are provided. In some embodiments, an
oxide material can include a substrate and a single-
crystal epitaxial layer of an
oxide composition disposed on a surface of the substrate, where the oxide composition is represented by ABO2 such that A is a
lithium cation, B is a cation selected from the group consisting of trivalent
transition metal cations, trivalent
lanthanide cations, trivalent
actinide cations, trivalent p-block cations, and combinations thereof, and O is an
oxygen anion. The unit
cell of
crystal structure of the oxide composition can be characterized by first layer of a plane of
lithium cations and a second layer of a plurality of edge-sharing octahedra having a B cation positioned in a center of each
octahedron and an
oxygen anion at each corner of each
octahedron. The first layer and the second layer of the unit
cell are alternatingly stacked along one axis of the unit
cell. Other aspects, features, and embodiments are also claimed and described.