The invention relates to a
hierarchical porous molecular sieve and a catalyst prepared from the
molecular sieve, specifically to a preparation method of a
hierarchical porous Beta
molecular sieve andan Ni catalyst thereof, and solves the problems of single pore structure, low
utilization rate, incomplete opening, only an adsorption role, easy
sintering, agglomeration and deactivation, and formation of
carbon deposit. The scheme includes: stirring deionized water,
sodium metaaluminate NaAlO2 and a dual template agent to obtain a clarified solution, adding
fumed silica and performing stirring,then transferring the mixture into a
polytetrafluoroethylene container, and conducting constant temperature heating and static
crystallization in a reaction kettle, then performing cooling, and carrying out high temperature
calcination, then taking
nickel carbonate tetrahydrate,
ammonium chloride and
ammonia water, and performing stirring in deionized water, adding the molecular
sieve and performing stirring, conducting
hydrothermal synthesis for certain period of time, then conducting washing and pumping
filtration, retaining the
solid product, and conducting
drying. The prepared hierarchicalporous Beta molecular
sieve is rich in micro-mesoporous biphasic highly interconnected pore structure. The prepared catalyst is core-shell-like structure catalyst, and has high yield.