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30results about How to "Lower concentration quenching" patented technology

Pyridazine iridium complexes containing alkyl steric-hindrance groups, and preparation method and application thereof

The invention discloses pyridazine iridium complexes containing alkyl steric-hindrance groups, and a preparation method and application thereof, belonging to the field of organic photoelectric materials. The objective of the invention is to overcome the problems that raw materials for preparation of conventional pyridazine tris-cyclometalated iridium complexes are expensive or have poor adaptability and that conventional iridium complexes are obvious in quenching of luminescence concentration. The pyridazine iridium complexes containing the alkyl steric-hindrance groups in the invention have a general structural formula as shown in a formula (1). The preparation method for the pyridazine iridium complexes comprises the following steps: systhesizing pyridazine ligands containing dicycloalkyl groups; and then reacting the pyridazine ligands containing the dicycloalkyl groups with IrCl3.(tht)3 so as to produce the pyridazine tris-cyclometalated iridium complexes. The prepared iridium complexes are obviously reduced in concentration quenching, and organic electronic luminescent devices prepared from the iridium complexes are greatly improved in doping concentration.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Fluoro phenylindole compound, application of fluoro phenylindole compound as red organic luminescent material, and preparation method of fluoro phenylindole compound

The invention discloses a fluoro phenylindole compound which adopts a structure shown in formula I, application of the fluoro phenylindole compound as a red organic luminescent material, and a preparation method of the fluoro phenylindole compound. The fluoro phenylindole compound is obtained through a reaction between cyclohexanone and 3-(3-(4-fluorophenyl)-1-isopropyl-1H-indole-2-yl) acrolein under an alkaline condition. The preparation method is simple to operate, convenient for synthesis and easy for purification; the obtained fluoro phenylindole compound is stable in structure and can be utilized for fluorescence conversion on a strong red color displayed under 800-nm laser excitation, thereby having potential application values in such fields as luminescent equipment, anti-counterfeit technologies, laser dye and fluorescence sensing; the research field of the fluoro phenylindole compound is expanded.
Owner:INST OF ANALYSIS GUANGDONG ACAD OF SCI (CHINA NAT ANALYTICAL

Iptycene-containing phosphorescent iridium complex and preparation method thereof and electroluminescent device

The invention discloses an iptycene-containing phosphorescent iridium complex and a preparation method thereof and an electroluminescent device and belongs to the field of organic photoelectric materials. The preparation method includes: dissolving 1-formyl triptycene into a dried organic solvent, and subjecting to condensation with an o-amino compound under protection of inert gas and in the presence of a catalyst to obtain cyclometalated ligand containing iptycene structure; dissolving IrCl3 in water, adding the cyclometalated ligand and the organic solvent, and stirring under protection of inert gas to obtain a dichloro-bridged intermediate of iridium; dissolving the dichloro-bridged intermediate in the organic solvent, and stirring with corresponding assistant ligand (L^X) under action of alkali and protection of nitrogen to obtain the iptycene-containing phosphorescent iridium complex. Aiming at the problem that iptycene iridium complexes in the prior art are not suitable for being applied to organic electroluminescent devices, a phosphorescent material wrapped by iptycene is taken as a luminous layer doped in an OLED (organic light-emitting diode) device, and high doping concentration, high spectrum stability and high efficiency can be realized.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Alkali metal lanthanum bismuthate gallate infrared optical glass and method for making same

InactiveCN101182118AGood chemical stabilityBroad Infrared Transmission CharacteristicsRefractive indexRoom temperature
The invention discloses an alkali metal lanthanum bismuth gallate infrared optical glass and a preparation method thereof. The main components of the glass are Bi2O3, Ga2O3, La2O3 and R2O. Its preparation method includes (1) mixing the powders of each component evenly, heating to 1000°C-1300°C, and keeping it for 2 to 5 hours; (2) pouring the melt into a mold and cooling it naturally; (3) forming the glass The sample is annealed and kept at a temperature of 300° C. to 400° C. for 20 to 30 hours, and then cooled to room temperature. The obtained glass has wide infrared transmission characteristics, the transmission range can reach 0.5-7μm, good thermal stability, the difference between the crystallization temperature and the transition temperature ΔT can reach 150°C and a large refractive index, according to different components, The refractive index can reach 2.4-2.5. It is used in optical fields such as infrared detection and optical communication.
Owner:JINAN UNIVERSITY

Ground limestone-based bismuth and europium co-doped yellow fluorescent powder

The invention discloses ground limestone-based bismuth and europium co-doped yellow fluorescent powder. According to the fluorescent powder, ground limestone is used as matrix, EU<3+> is used as an activating agent, Bi<3+> ions are used as a sensitizing agent, and alkali carbonate is used as a fluxing agent and a charge compensation agent; and the molar ratio of ground limestone to EU<3+> to Bi<3+> to M2CO3 is 100:(1-5):(1-15):(0.5-2.5), wherein M is one or more of Li<+>, Na<+> or K<+>. The invention also discloses a preparation method for the ground limestone-based bismuth and europium co-doped yellow fluorescent powder; and the preparation method comprises the following steps of: accurately weighing raw materials, fully grinding the raw materials in a ball grinding mill, mixing uniformly to form powder and thus obtaining precursor, pre-treating in a high-temperature furnace, grinding, calcining the precursor at CO2 atmosphere of standard atmospheric pressure, and grinding to obtain a sample. The provided preparation method for the fluorescent powder is simple, and the fluorescent powder is stable in performance, and high in luminous intensity and has important application value.
Owner:ZHEJIANG UNIV OF TECH

Organic-inorganic compound fluorescent powder, manufacturing method and application

The invention provides organic-inorganic compound fluorescent powder, a manufacturing method and application thereof. The method comprises the following steps of: immerging porous glass into the solution of an organic fluorescent material; taking the porous glass out after the porous glass absorbs the solution of the organic fluorescent material; and smashing the porous glass which absorbs the solution of the organic fluorescent material. The organic-inorganic compound fluorescent powder is prepared by the manufacturing method. The organic-inorganic compound fluorescent powder can be made into a light-emitting device by matching a semiconductor light-emitting diode in the range of between 200 and 550nm. The organic-inorganic compound fluorescent powder of the invention has a simple manufacturing process, can be doped into an encapsulating material of the semiconductor light-emitting diode, and solves the problem of a photochemical reaction between an organic light-emitting material and an organic encapsulating material.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD

Aromatic amine derivative containing benzophenone group and preparation method and application thereof

The invention discloses an aromatic amine derivative containing a benzophenone groupand a preparation method and application thereof. The aromatic amine derivative containing the benzophenone group provided by the invention has a unique triphenylamine group and the benzophenone group, has TICT and AIE effects, high luminous intensity and good hole transport ability, and can be used as a novel soluble light-emitting molecule which is good in performance, low in cost and highly distorted in space structure. The aromatic amine derivative can be widely applied to the fields of color display and solid-state lighting, and is used for preparing a luminescent material, a luminescent device or an intelligent material; when thearomatic amine derivative is used as OLED, the aromatic amine derivative containing the benzophenone group is taken as a host material and a phosphorescent material is taken as a guest material, so that the concentration quenching of the phosphorescent material can be reduced, the external quantum efficiency of the device is improved, and efficiency roll-off is reduced.
Owner:GUANGDONG UNIV OF TECH

Dendritic iridium complex electroluminescent material capable of solution processing and synthetic method thereof

The invention discloses a dendritic iridium complex electroluminescent material capable of solution processing and a synthetic method thereof. The molecular structure consists of two parts, one part is an iridium complex with room temperature phosphorescence property as a luminescent core, the other part is a racial with high triplet state energy level as a peripheral branch radial, and the two parts are connected through a non-conjugated radical. The molecule is of the structure as shown in the specification, wherein C1 to C3 are ionic dendritic iridium complexes, and C4 to C6 are neutral dendritic iridium complexes of similar structure. R1 and R2 are high triplet state energy level radicals with non-conjugated radical ends. The problems of synthesis, purification, device preparation technology and cost, existing in wet process preparation devices, of iridium complex materials can be solved.
Owner:SOUTHEAST UNIV

Alkali metal gallate glass and preparation method thereof

The invention discloses alkali metal gallate glass and a preparation method thereof. The glass comprises the following main components: Ga2O3, La2O3 and Na2O. The preparation method comprises the steps of (1) mixing powder of various components evenly, heating the power to 1550-1600 DEG C and keeping for 2-4h; (2) pouring a melt into a mold and naturally cooling; and (3) annealing a molded glass sample, keeping the temperature of 700-750 DEG C for 20-30h and then cooling to a room temperature. The glass has relatively good light absorption and emission characteristics and good thermal stability, and the refractive index can reach 1.7-1.8 according to different components. The alkali metal gallate glass can be applied to the optical field of optical waveguide and optical communication.
Owner:YUNNAN NORMAL UNIV

Fluorene and spiro-fluorene substituted phenylpyridine iridium complex and preparation method and application thereof

The invention belongs to the field of organic electroluminescent materials and relates to a fluorene and spiro-fluorene substituted phenylpyridine iridium complex and a preparation method and application thereof. The preparation method comprises the following steps of: synthesizing various fluorene and spiro-fluorene substituted phenylpyridine iridium ligands; reacting the ligands with iridium(III) chloride hydrate (IrCl3.3H2O) to obtain a chlorine-bridged dimer intermediate; and reacting the intermediate with acetylacetone in a proper solvent to obtain the fluorene and spiro-fluorene substituted phenylpyridine iridium complex. The iridium complex can change types and positions of the substituent of phenyl in a bidentateligand, can adjust luminous wavelength in a certain range and can be widely applied in the field of organic electroluminescence.
Owner:EAST CHINA NORMAL UNIV

Peripheral thermal cross-linking dendritic group, thermal cross-linking dendritic thermal activation delayed fluorescence material as well as synthesis method and application of thermal cross-linking dendritic thermal activation delayed fluorescence material

The invention discloses a peripheral thermal cross-linking dendritic group, a thermal cross-linking dendritic thermal activation delayed fluorescence material and a synthesis method and application thereof, and belongs to the field of organic photoelectric materials and organic light emitting diode devices. The molecular structure of the fluorescent material consists of three parts, wherein the first part is a luminous core with a thermal activation delayed fluorescence property; the second part is a carbazole group connected through a non-conjugated group and used as a peripheral dendritic group; and the third part is a styrene thermal crosslinking group connected to the periphery of the dendritic group. The novel material has the advantages that the steric hindrance effect of peripheraldendritic groups can effectively inhibit concentration quenching of triplet excitons, and the performance of a light-emitting device is improved; due to the introduction of alkyl chains, the solubility and the film-forming property of the material can be effectively enhanced; the introduction of the thermal crosslinking group can enhance the stability and film-forming property of a solid film. Thethermally activated delayed fluorescence material has good luminescence property and film-forming property, and is suitable for preparing organic electroluminescent devices by a wet method.
Owner:山西穿越光电科技有限责任公司

Thermal activation delayed fluorescence material capable of being processed by solution, preparation method and application thereof

The invention discloses a thermal activation delayed fluorescence material capable of being processed by a solution, a preparation method and application thereof. The thermal activation delayed fluorescence material capable of being processed by a solution comprises a molecular structure, the molecular structure is composed of two parts, one part is a core with a thermal activation delayed fluorescence property, the other part is a structure with a high triplet state energy level, at most one of R1 and R2 is hydrogen, the other parts are all connected with oxygen through benzene rings, and oxygen connection has a structure with a high triplet state energy level. The novel material has great advantages, the concentration quenching of triplet excitons can be effectively reduced through the steric hindrance effect of peripheral branched chains, and the performance of a light-emitting device is improved; the introduction of benzene rings can effectively enhance the solubility and film-forming property of the material. The thermal activation delayed fluorescence material capable of being processed by the solution has a relatively large molecular weight and good film-forming property, and is suitable for preparing an organic light-emitting device by a wet method. And along with the increase of the peripheral branched chains, the performance of the device is greatly improved.
Owner:SOUTHEAST UNIV

Compound, display panel and display device

The invention discloses a compound, a display panel and a display device. The compound has a structure represented by formula (1), wherein X, Y, R1, R2, R3, R4, R5, R6, R7, m1, m2, m3 and m4 are as defined in the invention, respectively. The compound provided by the invention can be used for the display panel and the display device.
Owner:WUHAN TIANMA MICRO ELECTRONICS CO LTD

A kind of dienyl phosphorescent iridium complex and its preparation method and electroluminescent device

The invention discloses a discenyl-containing phosphorescent iridium complex, a preparation method thereof and an electroluminescent device, belonging to the field of organic photoelectric materials. The 1-formyl tripcene is dissolved in a dry organic solvent, and under the protection of an inert gas and the presence of a catalyst, it undergoes condensation reaction with an ortho-amino compound to obtain a cyclometallation ligand containing a diene structure. IrCl 3 Dissolve in water, add a cyclometalation ligand containing a diene structure and an organic solvent, and stir under the protection of an inert gas to obtain a dichloro bridge intermediate of iridium. The dichloro bridge intermediate of iridium is dissolved in an organic solvent, and the corresponding auxiliary ligand (L^X) is stirred under nitrogen protection under the action of a base to obtain a discenyl iridium complex. Aiming at the problem that the discene-based iridium complexes in the prior art are not suitable for application in organic electroluminescent devices, the present invention uses the discene-wrapped phosphorescent material and uses it as the light-emitting layer doped in OLED devices to achieve High doping concentration, good spectral stability and high efficiency.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Fluorene and spiro-fluorene substituted phenylpyridine iridium complex and preparation method and application thereof

The invention belongs to the field of organic electroluminescent materials and relates to a fluorene and spiro-fluorene substituted phenylpyridine iridium complex and a preparation method and application thereof. The preparation method comprises the following steps of: synthesizing various fluorene and spiro-fluorene substituted phenylpyridine iridium ligands; reacting the ligands with iridium(III) chloride hydrate (IrCl3.3H2O) to obtain a chlorine-bridged dimer intermediate; and reacting the intermediate with acetylacetone in a proper solvent to obtain the fluorene and spiro-fluorene substituted phenylpyridine iridium complex. The iridium complex can change types and positions of the substituent of phenyl in a bidentateligand, can adjust luminous wavelength in a certain range and can be widely applied in the field of organic electroluminescence.
Owner:EAST CHINA NORMAL UNIV

A kind of solid broadband red light emitting organic luminescent material and preparation method thereof

The invention discloses a difunctional solid-state broadband red light emission organic light-emitting material having a structure shown in a formula I and a preparation method thereof. According to the solid-state broadband red light emission organic light-emitting material and the preparation method thereof disclosed by the invention, novel solid-state broadband red light emission piperidone organic light-emitting material with upconversion fluorescence characteristic are formed by combining piperidone with fluoro-phenylindole functional structure units through polyene bridged bonds. The difunctional solid-state broadband red light emission organic light-emitting materials provided by the invention have the characteristics of solid-state broadband red light emission and upconversion fluorescence, stable molecular structure, multiple functions, convenience in use and high practicality. (The formula I is shown in the description).
Owner:INST OF ANALYSIS GUANGDONG ACAD OF SCI (CHINA NAT ANALYTICAL

Multi-mode excited single-red-light nano fluorescent material and preparation method thereof

The invention discloses a multimode excited single-red-light nano fluorescent material and a preparation method thereof. The preparation method comprises the following steps: (1) respectively preparing aqueous solutions of YbCl3, ErCl3, MnCl2 and NaF with the concentration of 0.5-2.5 mmol / ml; (2) dissolving 0.3 g of NaOH in 2-6 ml of deionized water, adding 5-15 ml of ethanol and 5-15 ml of oleicacid, and stirring; (3) respectively adding the YbCl3 solution, the ErCl3 solution and the MnCl2 solution into the solution obtained in the step (2), and stirring; (4) adding 1-3 mmol of NaF into thesolution obtained in the step (3), and stirring; (5) transferring the solution in the step (4) into a high-pressure kettle, and carrying out a reaction for 100-400 minutes at the temperature of 140-240 DEG C to obtain a fluorescent product; and (6) after the fluorescence product in the step (5) is cooled to room temperature, centrifuging and washing to obtain the product.
Owner:HENAN UNIVERSITY

A multifunctional base pyridazinone compound, its application as an orange organic luminescent material and its preparation method

ActiveCN105061403BEfficient transferEnhanced conversion luminescence propertiesOrganic chemistryLuminescent compositionsQuinoxalineElectron donor
The invention discloses multifunctional group pyridazinone compounds, an application of the multifunctional group pyridazinone compounds serving as an orange organic light-emitting material and a preparation method of the multifunctional group pyridazinone compounds. Multiple functional structure units of anthryl, butadienyl, quinoxaline, pyridazinone and the like are effectively combined in one molecule, and one double-anthryl and butadienyl contained functional quinoxaline pyridazinone organic light emitting molecule is formed. According to the molecular structure, double anthryl (electron donor) for supplying electrons and one electron-deficient quinoxaline group (electron acceptor) exist in the molecule, three parts are connected through two butadiene structure units, and a larger and more extended D-pi-A-pi-D conjugated system is formed, and effective intramolecular charge transfer can be generated, so that enhancement of the up-conversion luminescence performance of organic materials is facilitated. The invention expands the field of research and application of the multifunctional group pyridazinone compounds.
Owner:INSTITUTE OF ANALYSIS GUANGDONG ACADEMY OF SCIENCES (CHINA NATIONAL ANALYTICAL CENTER GUANGZHOU)

Ground limestone-based bismuth and europium co-doped yellow fluorescent powder

The invention discloses ground limestone-based bismuth and europium co-doped yellow fluorescent powder. According to the fluorescent powder, ground limestone is used as matrix, EU<3+> is used as an activating agent, Bi<3+> ions are used as a sensitizing agent, and alkali carbonate is used as a fluxing agent and a charge compensation agent; and the molar ratio of ground limestone to EU<3+> to Bi<3+> to M2CO3 is 100:(1-5):(1-15):(0.5-2.5), wherein M is one or more of Li<+>, Na<+> or K<+>. The invention also discloses a preparation method for the ground limestone-based bismuth and europium co-doped yellow fluorescent powder; and the preparation method comprises the following steps of: accurately weighing raw materials, fully grinding the raw materials in a ball grinding mill, mixing uniformly to form powder and thus obtaining precursor, pre-treating in a high-temperature furnace, grinding, calcining the precursor at CO2 atmosphere of standard atmospheric pressure, and grinding to obtain a sample. The provided preparation method for the fluorescent powder is simple, and the fluorescent powder is stable in performance, and high in luminous intensity and has important application value.
Owner:ZHEJIANG UNIV OF TECH

A kind of solid broadband green light emitting crystal material and preparation method thereof

The invention discloses a solid broadband green-light emission crystal material which is as shown in a formula I. Indole and pyrazolone serving as functional structure units are combined through an aza butadiene bridge bond phase to form a bis-heterocyclic organic light-emitting crystal material of aza butadiene bridging. The material has good green-light emission characteristics in crystalline state and solution. The material serving as an organic light-emitting material is used for the fields of light-emitting devices, laser dyes, fluorescence sensing, anti-counterfeiting techniques and biomedical analysis.
Owner:INST OF ANALYSIS GUANGDONG ACAD OF SCI (CHINA NAT ANALYTICAL

A kind of fluorophenylquinoline phosphine oxide flame-retardant and luminescent bifunctional material and its preparation method

The invention discloses a fluorinated pheoylquinoline and phosphine oxide material with double functions of flame retardancy and light emitting shown in formula I and a preparation method thereof. A novel fluorinated pheoylquinoline and phosphine oxide compound with double functions of flame retardancy and light emitting is formed by combining two functional structure units, such as cyclopropyl fluorinated pheoylquinoline and phosphine oxide groups, so that a new variety of flame retardant agent and ultraviolet light emitting material is increased. The preparation method has the advantages that the technology is simple, the safety and environment-friendly effects are realized, and the preparation method is suitable for industrial production. The prepared luorinated pheoylquinoline and phosphine oxide material with double functions of flame retardancy and light emitting shown has the advantages that the dissolvability is good, the thermal stability and chemical stability are high, the processing property is good, the double functions of flame retardancy and light emitting are realized, the multi-element synergistic action of fluorine, phosphor and nitrogen is realized, the better flame-retardant efficiency is realized, the excellent solid ultraviolet light emitting characteristic is realized, and the application range is wide.
Owner:INSTITUTE OF ANALYSIS GUANGDONG ACADEMY OF SCIENCES (CHINA NATIONAL ANALYTICAL CENTER GUANGZHOU)
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