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30results about How to "Lower concentration quenching" patented technology

Pyridazine iridium complexes containing alkyl steric-hindrance groups, and preparation method and application thereof

The invention discloses pyridazine iridium complexes containing alkyl steric-hindrance groups, and a preparation method and application thereof, belonging to the field of organic photoelectric materials. The objective of the invention is to overcome the problems that raw materials for preparation of conventional pyridazine tris-cyclometalated iridium complexes are expensive or have poor adaptability and that conventional iridium complexes are obvious in quenching of luminescence concentration. The pyridazine iridium complexes containing the alkyl steric-hindrance groups in the invention have a general structural formula as shown in a formula (1). The preparation method for the pyridazine iridium complexes comprises the following steps: systhesizing pyridazine ligands containing dicycloalkyl groups; and then reacting the pyridazine ligands containing the dicycloalkyl groups with IrCl3.(tht)3 so as to produce the pyridazine tris-cyclometalated iridium complexes. The prepared iridium complexes are obviously reduced in concentration quenching, and organic electronic luminescent devices prepared from the iridium complexes are greatly improved in doping concentration.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Iptycene-containing phosphorescent iridium complex and preparation method thereof and electroluminescent device

The invention discloses an iptycene-containing phosphorescent iridium complex and a preparation method thereof and an electroluminescent device and belongs to the field of organic photoelectric materials. The preparation method includes: dissolving 1-formyl triptycene into a dried organic solvent, and subjecting to condensation with an o-amino compound under protection of inert gas and in the presence of a catalyst to obtain cyclometalated ligand containing iptycene structure; dissolving IrCl3 in water, adding the cyclometalated ligand and the organic solvent, and stirring under protection of inert gas to obtain a dichloro-bridged intermediate of iridium; dissolving the dichloro-bridged intermediate in the organic solvent, and stirring with corresponding assistant ligand (L^X) under action of alkali and protection of nitrogen to obtain the iptycene-containing phosphorescent iridium complex. Aiming at the problem that iptycene iridium complexes in the prior art are not suitable for being applied to organic electroluminescent devices, a phosphorescent material wrapped by iptycene is taken as a luminous layer doped in an OLED (organic light-emitting diode) device, and high doping concentration, high spectrum stability and high efficiency can be realized.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Peripheral thermal cross-linking dendritic group, thermal cross-linking dendritic thermal activation delayed fluorescence material as well as synthesis method and application of thermal cross-linking dendritic thermal activation delayed fluorescence material

The invention discloses a peripheral thermal cross-linking dendritic group, a thermal cross-linking dendritic thermal activation delayed fluorescence material and a synthesis method and application thereof, and belongs to the field of organic photoelectric materials and organic light emitting diode devices. The molecular structure of the fluorescent material consists of three parts, wherein the first part is a luminous core with a thermal activation delayed fluorescence property; the second part is a carbazole group connected through a non-conjugated group and used as a peripheral dendritic group; and the third part is a styrene thermal crosslinking group connected to the periphery of the dendritic group. The novel material has the advantages that the steric hindrance effect of peripheraldendritic groups can effectively inhibit concentration quenching of triplet excitons, and the performance of a light-emitting device is improved; due to the introduction of alkyl chains, the solubility and the film-forming property of the material can be effectively enhanced; the introduction of the thermal crosslinking group can enhance the stability and film-forming property of a solid film. Thethermally activated delayed fluorescence material has good luminescence property and film-forming property, and is suitable for preparing organic electroluminescent devices by a wet method.
Owner:山西穿越光电科技有限责任公司

Thermal activation delayed fluorescence material capable of being processed by solution, preparation method and application thereof

The invention discloses a thermal activation delayed fluorescence material capable of being processed by a solution, a preparation method and application thereof. The thermal activation delayed fluorescence material capable of being processed by a solution comprises a molecular structure, the molecular structure is composed of two parts, one part is a core with a thermal activation delayed fluorescence property, the other part is a structure with a high triplet state energy level, at most one of R1 and R2 is hydrogen, the other parts are all connected with oxygen through benzene rings, and oxygen connection has a structure with a high triplet state energy level. The novel material has great advantages, the concentration quenching of triplet excitons can be effectively reduced through the steric hindrance effect of peripheral branched chains, and the performance of a light-emitting device is improved; the introduction of benzene rings can effectively enhance the solubility and film-forming property of the material. The thermal activation delayed fluorescence material capable of being processed by the solution has a relatively large molecular weight and good film-forming property, and is suitable for preparing an organic light-emitting device by a wet method. And along with the increase of the peripheral branched chains, the performance of the device is greatly improved.
Owner:SOUTHEAST UNIV

A kind of dienyl phosphorescent iridium complex and its preparation method and electroluminescent device

The invention discloses a discenyl-containing phosphorescent iridium complex, a preparation method thereof and an electroluminescent device, belonging to the field of organic photoelectric materials. The 1-formyl tripcene is dissolved in a dry organic solvent, and under the protection of an inert gas and the presence of a catalyst, it undergoes condensation reaction with an ortho-amino compound to obtain a cyclometallation ligand containing a diene structure. IrCl 3 Dissolve in water, add a cyclometalation ligand containing a diene structure and an organic solvent, and stir under the protection of an inert gas to obtain a dichloro bridge intermediate of iridium. The dichloro bridge intermediate of iridium is dissolved in an organic solvent, and the corresponding auxiliary ligand (L^X) is stirred under nitrogen protection under the action of a base to obtain a discenyl iridium complex. Aiming at the problem that the discene-based iridium complexes in the prior art are not suitable for application in organic electroluminescent devices, the present invention uses the discene-wrapped phosphorescent material and uses it as the light-emitting layer doped in OLED devices to achieve High doping concentration, good spectral stability and high efficiency.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

Multi-mode excited single-red-light nano fluorescent material and preparation method thereof

The invention discloses a multimode excited single-red-light nano fluorescent material and a preparation method thereof. The preparation method comprises the following steps: (1) respectively preparing aqueous solutions of YbCl3, ErCl3, MnCl2 and NaF with the concentration of 0.5-2.5 mmol / ml; (2) dissolving 0.3 g of NaOH in 2-6 ml of deionized water, adding 5-15 ml of ethanol and 5-15 ml of oleicacid, and stirring; (3) respectively adding the YbCl3 solution, the ErCl3 solution and the MnCl2 solution into the solution obtained in the step (2), and stirring; (4) adding 1-3 mmol of NaF into thesolution obtained in the step (3), and stirring; (5) transferring the solution in the step (4) into a high-pressure kettle, and carrying out a reaction for 100-400 minutes at the temperature of 140-240 DEG C to obtain a fluorescent product; and (6) after the fluorescence product in the step (5) is cooled to room temperature, centrifuging and washing to obtain the product.
Owner:HENAN UNIVERSITY

A multifunctional base pyridazinone compound, its application as an orange organic luminescent material and its preparation method

ActiveCN105061403BEfficient transferEnhanced conversion luminescence propertiesOrganic chemistryLuminescent compositionsQuinoxalineElectron donor
The invention discloses multifunctional group pyridazinone compounds, an application of the multifunctional group pyridazinone compounds serving as an orange organic light-emitting material and a preparation method of the multifunctional group pyridazinone compounds. Multiple functional structure units of anthryl, butadienyl, quinoxaline, pyridazinone and the like are effectively combined in one molecule, and one double-anthryl and butadienyl contained functional quinoxaline pyridazinone organic light emitting molecule is formed. According to the molecular structure, double anthryl (electron donor) for supplying electrons and one electron-deficient quinoxaline group (electron acceptor) exist in the molecule, three parts are connected through two butadiene structure units, and a larger and more extended D-pi-A-pi-D conjugated system is formed, and effective intramolecular charge transfer can be generated, so that enhancement of the up-conversion luminescence performance of organic materials is facilitated. The invention expands the field of research and application of the multifunctional group pyridazinone compounds.
Owner:INSTITUTE OF ANALYSIS GUANGDONG ACADEMY OF SCIENCES (CHINA NATIONAL ANALYTICAL CENTER GUANGZHOU)

A kind of fluorophenylquinoline phosphine oxide flame-retardant and luminescent bifunctional material and its preparation method

The invention discloses a fluorinated pheoylquinoline and phosphine oxide material with double functions of flame retardancy and light emitting shown in formula I and a preparation method thereof. A novel fluorinated pheoylquinoline and phosphine oxide compound with double functions of flame retardancy and light emitting is formed by combining two functional structure units, such as cyclopropyl fluorinated pheoylquinoline and phosphine oxide groups, so that a new variety of flame retardant agent and ultraviolet light emitting material is increased. The preparation method has the advantages that the technology is simple, the safety and environment-friendly effects are realized, and the preparation method is suitable for industrial production. The prepared luorinated pheoylquinoline and phosphine oxide material with double functions of flame retardancy and light emitting shown has the advantages that the dissolvability is good, the thermal stability and chemical stability are high, the processing property is good, the double functions of flame retardancy and light emitting are realized, the multi-element synergistic action of fluorine, phosphor and nitrogen is realized, the better flame-retardant efficiency is realized, the excellent solid ultraviolet light emitting characteristic is realized, and the application range is wide.
Owner:INSTITUTE OF ANALYSIS GUANGDONG ACADEMY OF SCIENCES (CHINA NATIONAL ANALYTICAL CENTER GUANGZHOU)
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