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This invention belongs to the field of thermal energy recovery and automation control, specifically relating to an intelligent control system for mine water waste heat recovery. The system includes a production condition sensing device, a multi-source thermal monitoring device, an energy value analysis center, a dynamic load dispatching terminal, a multi-media heat exchange actuator, and a flexible thermal energy storage system. The system collects real-time mine production conditions and multi-source thermal parameters, constructs an energy asset model using a discrete state transition probability model, and, based on a game theory bidding mechanism and electricity price fluctuation trend prediction, guides the heat exchange actuator and storage system to perform optimized allocation and predictive storage of thermal energy. This invention transforms fluctuating heat sources into predictable energy assets, achieving the lowest-cost and most energy-efficient energy configuration scheme in a multi-source coupled environment, improving resource utilization, and ensuring the stability of energy supply in the mining area.