This invention relates to a method for preparing photocurable high
thermal conductivity aluminum
nitride ceramic irregular parts based on the synergistic regulation of
residual carbon and
yttrium fluoride, comprising the following steps: S1, preparing a photocurable resin
system; S2, adding aluminum
nitride powder,
yttrium fluoride, and a dispersant to the photocurable resin
system to obtain a
composite ceramic slurry suitable for photocurable 3D printing; S3, curing layer by layer to obtain an aluminum
nitride ceramic irregular part
green body; S4, placing the
ceramic green body obtained in step S3 in an
atmosphere sintering furnace for two-step debinding; S5, taking a
small sample of the debinded sample obtained in step S4 for
residual carbon content calibration; S6,
sintering to obtain the aluminum nitride ceramic irregular part. This invention precisely controls the
residual carbon content after debinding by designing photocurable
monomer combinations with specific functionalities, and simultaneously uses
yttrium fluoride sintering aid to achieve a
triple effect of densification, removal of
lattice oxygen, and absence of
liquid phase residue. The residual carbon regulation and the synergistic effect of the aid complement each other to jointly achieve the preparation of high
thermal conductivity aluminum nitride ceramic irregular parts.