The invention discloses a periodic non-sinusoidal wave reference of an electronic current transformer with a current booster, comprising a main iron core of the current booster, an auxiliary iron core of the current booster, a reference main iron core, a reference auxiliary iron core, a fundamental wave power supply supplying coil, a harmonic wave power supplying coil, a primary coil, a secondary coil, a detection coil of the current booster, a compensation coil of the current booster, a reference detection coil, a reference compensation coil, a compensation mechanism, a pure resistive built-in precise resistor, an operational amplifier and a secondary coil shielding layer. By adopting the invention, the primary test current of the periodic non-sinusoidal wave for verifying the accuracy of the electronic current transformer can be generated, and the secondary standard reference voltage in linear proportional relation with the primary test current of the periodic non-sinusoidal wave can be output, the limitations of verification accuracy for the fundamental wave and the harmonic wave of the traditional electronic current transformer under the condition of the single frequency is overcome, and the non-linear phenomenon of the electronic current transformer is verified.