The invention relates to a liquid film dedusting device which is used in a desulfurizer, has a simple structure, can be used for effectively removing smoke dust and liquid drops in flue gas, and is free of secondary pollution. The liquid film dedusting device comprises a dedusting assembly formed by multiple layers of dedusting units, a water inlet header, a water return header, a circulating water pump and a circulating waterway, wherein each layer of dedusting units comprises a plurality of diversion pieces in parallel, a gap is formed between each two adjacent diversion pieces, the diversion pieces of each two adjacent layers of dedusting units are staggered in parallel to rectify flue gas, a water inlet of each diversion piece is communicated with the water inlet header, a water outlet of each diversion piece is communicated with the water return header, the water return header is communicated with the water inlet header via the circulating waterway and the circulating water pump in sequence to form a continuous path, the continuous path is filled with a cooling liquid, and the cooling liquid is used for cooling via air cooling when flowing in a pipeline outside the desulfurizer and is driven by the circulating pump to flow in a continuous circulating manner to precool vapor and liquid drops in flue gas in the desulfurizer to form liquid films on the outer walls of the diversion pieces.