The present invention is a method for the manufature of a
membrane structure for use in electrochemical conversions. The method includes providing a first mixture at a first temperature and a second mixture at a second temperature, extruding the first mixture to form a plurality of spaced-apart supportable membranes, cooling the extruded membrane from the first temperature to a third temperature, forming sufficient bubble surfaces of the second mixture between the membranes to facilitate the support of the membranes, cooling the extruded membranes and the formed bubble surfaces to a semi-
solid from the second temperature to the third temperature less than the first and second temperatures, heating the cooled extruded membranes and the cooled formed bubble surfaces from the semi-
solid at the third temperature to a predetermined elevated temperature sufficient to make the extruded membranes and the formed bubble surfaces into a
sintered ceramic, and sufficiently cooling the extruded membranes and the formed bubble surfaces in the
sintered ceramic to cause the bubbles to support the membranes.