The invention discloses a bacterial composition containing oxalate diacetonamine copper and a benzimidazole bactericide. The bacterial composition comprises a first active ingredient and a second active ingredient. Weight ratio of the first active ingredient to the second active ingredient is 1:15-15:1. The first active ingredient is oxalate diacetonamine copper. The second active ingredient is one ingredient selected from thiophanate methyl, carbendazim, benomyl and thiabendazole. The composition can be made up into water dispersible granules, a wettable powder, a suspending agent or a dispersible oil suspension which is allowed for use in agriculture, and has a good effect of controlling powdery mildew of cucumber, cucumber downy mildew, botrytis cinerea, tomato early blight, apple altermaria leaf spot, apple brown spot, apple mildew or potato late blight. By the use of the bacterial composition, the problem that oxalate diacetonamine copper or the above benzimidazole bactericide has non-ideal control effects when separately used is solved effectively. By two-component compounding, the bacterial composition has remarkable synergism and has good safety for crops, and resistance risks and drug delivery costs are reduced.