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Silicon-carbon composite material with nano micropores and preparation method as well as application thereof

The invention discloses a silicon-carbon composite material with nano micropores and a preparation method as well as application thereof. The material comprises nano-silicon (Si) particles and a carbon nanofiber matrix, wherein the nano-silicon particles are dispersed in the carbon nanofiber matrix; and nano pores and micropores communicated with the nano pores are distributed in the carbon nanofiber matrix. The method comprises the steps of dissolving the nano-Si particles and polyacrylonitrile (PAN) in a solvent to prepare a mixed spinning solution, then carrying out electrostatic spinning on the mixed spinning solution, and curing spinning trickles in a coagulating bath to obtain a porous PAN-Si composite nanofiber; and then carrying out oxidation and carbonization treatment in sequence to obtain the silicon-carbon composite material with a nano micropore structure. The silicon-carbon composite material is applied to preparation of lithium ion battery cathode materials. Compared with the prior art, the silicon-carbon composite material ensures the overall electron transport capacity of the material while reserving buffer space for expansion of the nano-Si particles.
Owner:深圳石墨烯创新中心有限公司

Silicon-carbon composite material with nano micropores and preparation method as well as application thereof

The invention discloses a silicon-carbon composite material with nano micropores and a preparation method as well as application thereof. The composite material comprises nano-silicon (Si) particles and a carbon nanofiber matrix, wherein nano pores and micropore channels communicated with each other are distributed in the carbon nanofiber matrix; the nano-Si particles are distributed in the carbon nanofiber matrix; one part of the nano-Si particles are embedded in the carbon nanofiber matrix; and the other part of the nano-Si particles are positioned in the nano pores. The method comprises the steps of carrying out electrostatic spinning on a polyacrylonitrile (PAN) spinning solution doped with the nano-Si particles and a polymer pore former (PPM) to obtain a PAN-Si-PPM composite nanofiber, and then carrying out oxidation and carbonization to obtain the silicon-carbon composite material. The silicon-carbon composite material is applied to preparation of lithium ion battery cathode materials. Compared with the prior art, the silicon-carbon composite material ensures the overall electron transport capacity of the material while reserving buffer space for expansion of the nano-Si particles.
Owner:深圳石墨烯创新中心有限公司
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