The present invention discloses a low-temperature
plasma disproportionation reaction unit, which includes a U-shaped tube, and a double
dielectric rod-cylinder type barrier
discharge structure arranged on its straight
pipe section, and a seal combining a double
ceramic sheet and an organic insulating medium is provided at the top. A
disproportionation reactor based on the reaction unit is also proposed, which mainly includes a filter, a flow controller, a first
oxygen analyzer, a first
buffer tank, a second
oxygen analyzer, a low-temperature
plasma disproportionation reaction unit, and a second
buffer tank that are sequentially connected in series and located in a heat preservation layer. Finally, a disproportionation reaction method based on the disproportionation reactor is also proposed, which mainly includes purification, flow control,
oxygen analysis to eliminate
hydrogen explosion, low-temperature
plasma disproportionation reaction, and gas
component analysis to evaluate the reaction efficiency. The disproportionation reaction unit, reactor, and reaction method can achieve low-temperature disproportionation reaction, without the problems of
noble metal catalyst shedding and
tritium-containing
waste generation, and at the same time have high conversion efficiency, fast
reaction speed, and low
operating cost.